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CN-121971352-A - Liquid crystal phase plant hair dye based on quaternary plant synergistic effect and application thereof

CN121971352ACN 121971352 ACN121971352 ACN 121971352ACN-121971352-A

Abstract

The invention relates to the technical field of plant hair dyes, in particular to a liquid crystal phase plant hair dye based on quaternary plant synergy and application thereof, which comprises quaternary color development components, a surface activation system, functional auxiliary materials and an oxidation activator according to 100 parts of total materials, wherein the mass ratio of the quaternary color development components to the surface activation system is 3-5:1, the preparation process comprises the steps of separately preparing the quaternary color development components, embedding treatment, compounding treatment, liquid crystal phase forming treatment, homogenizing treatment, quality detection and packaging, the application scene covers white hair covering, creative hair dyeing and hair dyeing operation of scalp care adaptation, and the invention aims to provide the liquid crystal phase plant hair dye based on quaternary plant synergy and application thereof, so as to solve the problems that the existing plant hair dye mostly depends on single or few plant raw materials, lacks of multi-component synergistic design, causes limited color development capability, insufficient color development depth, and poor color fixing effect.

Inventors

  • CHENG CHUNSONG
  • BU XIANGLONG
  • ZHAO JIHUI

Assignees

  • 江西省、中国科学院庐山植物园
  • 庐山杏林中药植物研究所

Dates

Publication Date
20260505
Application Date
20260129

Claims (10)

  1. 1. The liquid crystal phase plant hair dye based on quaternary plant synergistic effect and application thereof are characterized by comprising quaternary color development components, a surface activation system, functional auxiliary materials and an oxidation activator according to 100 parts of total materials, wherein the mass ratio of the quaternary color development components to the surface activation system is 3-5:1, the preparation process comprises the steps of separately preparing the quaternary color development components, embedding treatment, compounding treatment, liquid crystal phase forming treatment, homogenizing treatment, quality detection and packaging, and the application scene comprises white hair covering, creative hair dyeing and hair dyeing operation with scalp care adaptation.
  2. 2. The liquid crystal phase plant hair dye based on quaternary plant synergistic effect and application thereof according to claim 1, wherein the quaternary color development component comprises a galli gall aqueous extract, an eclipta alba alcohol extract, a polygonum multiflorum tuberosum tuberous root enzymatic hydrolysis extract, an blueberry leaf CO 2 supercritical extract, wherein the galli gall aqueous extract contains more than or equal to 200mg/g tannic acid, 35 parts, the extract is prepared by extracting through a stainless steel extraction tank, filtering through a plate-frame filter press and concentrating through a rotary evaporator, the eclipta alba alcohol extract Huai De contains more than or equal to 7mg/g, 10 parts, the extract is prepared by extracting through a microwave extraction instrument, concentrating through a reduced pressure distillation device and drying through a vacuum drying box, the polygonum multiflorum tuber enzymatic hydrolysis extract contains more than or equal to 2.5mg/g, the blueberry leaf CO 2 supercritical extract contains more than or equal to 12mg/g, the blueberry anthocyanin content is prepared by enzymolysis in an enzymolysis tank, inactivating enzyme by boiling water and filtering concentration, and the blueberry leaf CO 2 supercritical extract contains 8 parts and the blueberry anthocyanin content is prepared by extracting through a CO 2 supercritical extraction instrument.
  3. 3. The quaternary plant synergistic liquid crystal phase plant hair dye and application thereof according to claim 1, wherein the surface activation system comprises soapberry pericarp saponin, gleditsia sinensis saponin, glossy privet fruit long-chain fatty acid and C22 alkanol, wherein the soapberry pericarp saponin content is more than or equal to 60%, the soapberry pericarp saponin content is more than or equal to 75%, the gleditsia sinensis saponin content is 6%, the C20-C24 saturated fatty acid content in the glossy privet fruit long-chain fatty acid is more than or equal to 45% and 6%, the C22 alkanol is a surface active auxiliary component, and the HLB value of the surface activation system is 11.5.
  4. 4. The quaternary plant synergistic liquid crystal phase plant hair dye and application thereof according to claim 1, wherein the functional auxiliary materials comprise beta-cyclodextrin, deionized water and food-grade vitamin E, wherein the purity of the beta-cyclodextrin is more than or equal to 99%, the content of the beta-cyclodextrin is 8 parts, the conductivity of the deionized water is less than or equal to 0.01mS/m, the conductivity of the deionized water meets the GB/T6682 first-level water standard, the content of the food-grade vitamin E is 10 parts, the purity of the food-grade vitamin E is more than or equal to 96%, and the content of the food-grade vitamin E is natural dl-alpha-tocopherol, and the content of the food-grade vitamin E is 2 parts.
  5. 5. The quaternary plant synergistic liquid crystal phase plant hair dye and the application thereof according to claim 1, wherein the oxidation activator is 0.3% Fe 2+ solution, is prepared from ferrous sulfate with purity not less than 99.5% and no caking and deliquescence, is matched with a main material according to a mass ratio of 1:10, is independently stored in a sealing manner, is subjected to oxidation triggering by a gradient oxidation method, and is sprayed after the hair dye contacts hair for 10 min.
  6. 6. The quaternary plant synergistic liquid crystal phase plant hair dye and the application thereof according to claim 1, wherein the embedding treatment is that tannic acid in the galling water extract and beta-cyclodextrin are mixed according to the mass ratio of 1:0.23, and are treated by an ultrasonic cell disruptor after deionized water is added, wherein the power of the ultrasonic cell disruptor is 300W, the frequency is 40kHz, the treatment temperature is less than or equal to 40 ℃, the treatment time is 20min, and the embedding rate is more than or equal to 85%.
  7. 7. The quaternary plant synergistic liquid crystal phase plant hair dye and application thereof according to claim 1, wherein the compounding treatment comprises compounding and stepwise compounding of a surface activation system, wherein the surface activation system is prepared by adding soapberry pericarp saponin, gleditsia sinensis saponin, glossy privet fruit long-chain fatty acid and C22 alkanol into a low-temperature mixer, mixing at a temperature of 25+/-2 ℃, rotating speed of 60r/min and mixing time of 15min, the stepwise compounding is prepared by adding an embedding compound into the surface active compounding system, and the rotating speed of the low-temperature mixer is adjusted to 80r/min and mixing for 20min.
  8. 8. The quaternary plant synergistic liquid crystal phase plant hair dye and the application thereof according to claim 1, wherein the liquid crystal phase forming treatment is characterized in that materials subjected to step-by-step compounding are transferred to ultrasonic auxiliary equipment for treatment, the power of the ultrasonic auxiliary equipment is 200W, the frequency is 30kHz, the treatment time is 30min, samples are taken every 10min in the treatment process, a layered liquid crystal structure is confirmed by a liquid crystal phase detector through XRD detection, the spacing d=4.6 nm of liquid crystal layers and the contact angle are smaller than 30 DEG, food-grade vitamin E is added into a mixed system after the liquid crystal phase forming treatment, the high-pressure homogenizer is put into the homogenizing pressure for 30MPa, the temperature is 30 ℃, the homogenizing times are 2 times, the particle size D 50 mu m of the homogenized system is smaller than or equal to 5 mu m, and the particle size distribution is detected by a laser particle size analyzer.
  9. 9. The quaternary plant synergistic liquid crystal phase plant hair dye and application thereof according to claim 1 are characterized in that the quality detection comprises component detection and performance detection, wherein the component detection adopts an HPLC-UV/MS combined instrument, an ICP-MS detector and a GC-MS detector, the HPLC-UV/MS combined instrument is provided with a C18 chromatographic column, the mobile phase is 0.1% formic acid water-acetonitrile gradient elution, the total heavy metal content is less than or equal to 10ppm, the benzopyrene is not detected by the GC-MS detector, the performance detection adopts a color difference meter and an ultraviolet aging test box, a spot patch test is carried out, the packaging adopts a double-chamber packaging bottle, the quantitative filling is carried out through a full-automatic filling machine, the filling precision is +/-0.1 g, the batch number and the quality guarantee period of the packaged spray printing production are detected through a bag leakage detector, and the packaging tightness is detected through the bag leakage detector.
  10. 10. The quaternary plant synergistic liquid crystal phase plant hair dye and the application thereof according to claim 1 are characterized in that the liquid crystal phase plant hair dye is applied to white hair according to hair dyeing operation when white hair is covered, and is matched with an oxidation activator for use, the ratio of CO 2 supercritical extract of blueberry leaves is adjusted when creatively dyeing hair, continuous color change from hazelnut brown to sandalwood black is realized, long-time insolation is avoided when the liquid crystal phase plant hair dye is used, and the hair dye is treated according to a conventional washing and protecting process after dyeing hair.

Description

Liquid crystal phase plant hair dye based on quaternary plant synergistic effect and application thereof Technical Field The invention relates to the technical field of plant hair dyes, in particular to a liquid crystal phase plant hair dye based on quaternary plant synergistic effect and application thereof. Background The plant hair dye takes natural plant extracts as core color development and functional components to replace synthetic pigments and irritant additives in the chemical hair dye, and realizes the hair dyeing effect through the interaction of plant active components, and has the advantages of mildness, safety and natural properties; The existing plant hair dye is mostly dependent on single or few plant raw materials, and lacks of multi-component cooperative design, so that the color developing capability is limited, the color developing depth is insufficient, the combination of pigment components and hair is not firm enough, and the color fixing effect is poor. Disclosure of Invention The invention aims to provide a liquid crystal phase plant hair dye based on quaternary plant synergistic effect and application thereof, and aims to solve the problems that the existing plant hair dye in the background art is mostly dependent on single or few plant raw materials, lacks of multi-component synergistic design, and is limited in color development capability, insufficient in color development depth, insufficient in firm combination of pigment components and hair and poor in color fixing effect. The liquid crystal phase plant hair dye comprises quaternary color development components, a surface activation system, functional auxiliary materials and an oxidation activator according to 100 parts of total materials, wherein the mass ratio of the quaternary color development components to the surface activation system is 3-5:1, the preparation process comprises the steps of separately preparing the quaternary color development components, embedding treatment, compounding treatment, liquid crystal phase forming treatment, homogenizing treatment, quality detection and packaging, and the application scene comprises white hair covering, creative hair dyeing and hair dyeing operation of scalp nursing adaptation. Preferably, the quaternary color development component comprises a galli gall aqueous extract, an eclipta alba ethanol extract, a polygonum multiflorum tuberosum tuberous root enzymatic hydrolysate and a blueberry leaf CO 2 supercritical extract, wherein the galli gall aqueous extract contains more than or equal to 200mg/g of tannic acid, 35 parts, the galli gall aqueous extract is prepared by extracting in a stainless steel extraction tank, filtering in a plate-and-frame filter press, concentrating by a rotary evaporator, the eclipta alba ethanol extract contains more than or equal to 7mg/g of lactone, 10 parts, the eclipta alba ethanol extract contains more than or equal to 10 parts, the eclipta alba ethanol extract is prepared by extracting in a microwave extractor, concentrating by a reduced pressure distillation device, drying by a vacuum drying oven, the polygonum multiflorum tuberous root enzymatic hydrolysate contains more than or equal to 2.5mg/g of free anthraquinone, 7 parts, the blueberry leaf CO 2 supercritical extract contains more than or equal to 12mg/g of anthocyanin, and 8 parts, and the blueberry leaf CO 2 supercritical extract is prepared by extracting by a CO 2 supercritical extractor. Preferably, the surface activation system comprises soapberry pericarp saponin, gleditsia sinensis saponin, glossy privet fruit long-chain fatty acid and C22 alkanol, wherein the soapberry pericarp saponin content is more than or equal to 60%, the gleditsia sinensis saponin content is more than or equal to 75%, the gleditsia sinensis saponin content is 6%, the C20-C24 saturated fatty acid in the glossy privet fruit long-chain fatty acid is more than or equal to 45% and 6%, the C22 alkanol is a surface active auxiliary component, and the HLB value of the surface activation system is 11.5. Preferably, the functional auxiliary materials comprise beta-cyclodextrin, deionized water and food-grade vitamin E, wherein the purity of the beta-cyclodextrin is more than or equal to 99%, the content of the beta-cyclodextrin is 8 parts, the conductivity of the deionized water is less than or equal to 0.01mS/m, the deionized water meets the GB/T6682 primary water standard, the content of the deionized water is 10 parts, the purity of the food-grade vitamin E is more than or equal to 96%, and the food-grade vitamin E is natural dl-alpha-tocopherol, and the content of the food-grade vitamin E is 2 parts. Preferably, the oxidation activator is 0.3% Fe 2+ solution, is prepared from ferrous sulfate with purity of more than or equal to 99.5% and no caking or deliquescence, is matched with a main material according to the mass ratio of 1:10, is independently stored in a sealing way, and is sprayed after hair dye is contac