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CN-121991710-A - Cleaning product collection prepared from environmental waste

CN121991710ACN 121991710 ACN121991710 ACN 121991710ACN-121991710-A

Abstract

The invention provides a clean product collection prepared from environmental garbage, which is characterized in that the collection comprises a solid fuel product subset 1, or a total solid fuel product subset 2 which comprises crude pyroligneous liquor or/and refined pyroligneous liquor or/and impurity-removed emulsified tar product subset 2, wherein the subset 1 is prepared by combining any one of A, B, C, D four materials with any one or more of the rest three materials or taking only independent C, and under the frame that the sum of the weight parts of all varieties of materials is constant equal to 10 weight parts, the weight part ratio of the materials of W A /W B /W C /W D is changed within the range of 0-9.9/0-8/0-10/0-6, and specifically comprises biomass garbage in an environment which is not or hardly odorized by A, biomass garbage in a deodorized environment after fermentation, C is at least prepared by the residue of A or B, and dry distilled garbage in the environment which is D or waste plastic in a commercial waste collection.

Inventors

  • CHEN HUIHONG
  • Request for anonymity
  • TANG YUHAO
  • TANG HONGWEI
  • HU JIAQING
  • SHA LIANGBAO

Assignees

  • 朱兵
  • 陈汇宏
  • 唐禹豪
  • 胡嘉庆
  • 沙良宝

Dates

Publication Date
20260508
Application Date
20230524
Priority Date
20221229

Claims (15)

  1. 1. The cleaning product set prepared from the environmental garbage is characterized in that the cleaning product set comprises a solid fuel product subset 1, or the subset 1 and another emulsified tar product subset 2 which comprises crude pyroligneous liquor, or/and refined pyroligneous liquor, or/and impurity removal; The 'subset 1' is specifically formed by combining any one of A, B, C, D varieties of materials with any one or more of the rest three varieties of materials, or taking independent C, and forming a total solid fuel product set 1 by different changes of the weight part ratio W A /W B /W C /W D of the varieties of materials within the range of 0-9.9/0-8/0-10/0-6 under the frame that the weight part sum W A +W B +W C +W D of the varieties of materials is equal to 10 weight parts, wherein the 'A, B, C, D' materials specifically refer to: A is biomass garbage in an environment which is not or is difficult to smell, B, fermenting the biomass garbage in the deodorized and disinfected environment, C is at least prepared from the residue of the carbonization of the A or/and B, D, waste plastics in the environmental garbage or/and waste plastics purchased from commercial collection; however, when only independent C is used, namely "W A /W B /W C /W D " is used in a weight ratio of "0/0/10/0", the corresponding dry distillation raw material of C must contain B material; The sub-collection 2 specifically comprises crude pyroligneous liquor obtained by condensing distillation components during the carbonization in the C, or the crude pyroligneous liquor is collected by a rectification, condensation, room temperature or low temperature temporary storage tank, or the refined pyroligneous liquor with the boiling range temperature of 85-190 ℃ under normal pressure and purified by adsorption filtration of active carbon only for the rectification collection liquid with the boiling range temperature of 100-190 ℃ under normal pressure, or the emulsified tar with the polycyclic aromatic hydrocarbon impurity removed is obtained by rectification to remove volatile matters below 190 ℃ and emulsification and active carbon adsorption treatment for tar at the bottom of the rectification tower.
  2. 2. The subset of solid fuel products 1 "of claim 1, further characterized by: The method of claim 1, wherein the waste cotton wool, waste furniture, waste fungus sticks of edible fungi, camphor tree leaves residues of refined oil, deactivated activated carbon residues discarded in the processes of sugar-making, pharmacy and decolorization of oil industry, crushed materials of any one or more combination of discarded straws, dried rattan, seed husks, and branches and fallen leaves discarded in the process of road or woodland/landscaping, or crushed materials after glass/stone/metal removal are separated; The process of claim 1, wherein the process comprises the steps of (a) preparing biogas residue, kitchen waste, food waste, kitchen waste, livestock and poultry manure, chinese medicinal residue discarded in the Chinese patent medicine industry, mycelium fermentation residue discarded in the biochemical industry, sludge discharged in a domestic sewage purification sedimentation tank, floating garbage old material dug from a landfill site, domestic garbage old material dug from a landfill site, crushed product of any one or more of wet/dry garbage collected daily from society, or crushed product obtained by separating and removing glass/stone/metal; The "C" according to claim 1, which comprises at least the carbon residue left after the removal of glass/stone/metal by distillation and separation from the above-mentioned "A" or/and the above-mentioned "B", or the deactivated activated carbon having adsorbed polycyclic aromatic hydrocarbon and pigment impurities, which is produced by purifying the condensate of the re-distillation of the distillation fraction by adsorption or purifying the tar produced by the re-distillation of the distillation fraction; The method of claim 1, wherein the method comprises the steps of (1) selecting one or more of agricultural waste plastic film materials, fishery waste plastic net/floating ball, waste plastic lawn for sports ground replacement, waste plastic product/fabric containing chemical fiber, waste plastic containing miscellaneous waste obtained from waste furniture, waste plastic film materials discarded in waste paper recycling industry, waste plastic/plastic miscellaneous waste leftovers discarded in shoe industry, broken materials of any one or more combination of waste plastic film leftovers discarded in packaging and printing industry, or crushed materials or clusters/extruded strips/particles after glass/stone/metal removal; The solid fuel product set according to claim 1, wherein the total solid fuel product set is formed by different changes of the weight ratio of the various materials ' W A /W B /W C /W D ' in the range of 0 to 9.9/0 to 8/0 to 10/0 to 6' under the condition that the sum of the weight parts of the various materials ' W A +W B +W C +W D ' is equal to 10 weight parts, and the solid fuel product set comprises at least any one or more of the following 1) to 11) in subdivision: 1) When the combination of A and B is adopted, that is, W C 、W D is equal to 0 weight part, the proper weight ratio of W A /W B /W C /W D can be changed within the range of 9.9-5/0.1-5/0/0; Or/and 2) when the combination of A and C is adopted, that is, W B 、W D is equal to 0 weight part, the proper weight ratio of W A /W B /W C /W D can be changed within the range of 0.1-9.9/0/9.9-0.1/0; Or/and 3) when the combination of A and D is adopted, that is, when W B 、W C is equal to 0 weight part, the proper weight ratio of W A /W B /W C /W D can be changed within the range of 9~4/0/0/1-6; or/and 4) when the combination of A, B and C is taken, that is, W D is equal to 0 weight part, the proper weight ratio of W A /W B /W C /W D can be changed in the range of 7.9-1.9/2-0.1/0.1-8/0, or can be changed in the range of 1-1.9/8-0.1/1-8/0; or/and 5) when the combination of A, C and D is taken, that is, W B is equal to 0 weight part, the proper weight ratio of W A /W B /W C /W D can be changed in the range of 7.9-2/0/0.1-2/2-6 or can be changed in the range of 4-5/0/5~2/1-3; Or/and 6) when the combination of A, B and D is taken, that is, W C is equal to 0 weight part, the proper weight ratio of W A /W B /W C /W D can be changed in the range of 4~2/5~2/0/1-6 or can be changed in the range of 64/3-2/0/1-4; or/or 7) when A, B, C and D are combined, the proper weight ratio of W A /W B /W C /W D can be changed in the range of 6~2/0.1-1/2-1/1.9-6 or can be changed in the range of 1-7/8-0.1/0.1-0.4/0.9-2.5; Or/and 8) when the combination of B and C is adopted, namely W A 、W D is equal to 0 weight part, the proper weight ratio of W A /W B /W C /W D can be changed in the range of 0/5-0.1/5-9.9/0, or can be changed in the range of 0/2-8/8~2/0; Or/and 9) when the combination of B and D is adopted, namely when W A 、W C is equal to 0 weight part, the proper weight ratio of W A /W B /W C /W D can be changed within the range of 0/8~4/0/2-6; or/and 10) when the combination of C and D is adopted, that is, W A 、W B is equal to 0 weight part, the proper weight ratio of W A /W B /W C /W D can be changed within the range of 0/0/9~4/1-6; Or/and 11) when the combination of B and C and D is taken, that is, W A is equal to 0 weight part, the proper weight ratio of W A /W B /W C /W D can be changed in the range of 0/3-1/2-7/5~3, or can be changed in the range of 0/3-2/6~2/1-6.
  3. 3. The solid fuel product collection 1 according to claim 1, or a combination of any one or more of alkaline auxiliary materials such as lime, calcium carbonate, raw vermiculite powder, which prevent ashes from being sintered, or an acidic auxiliary material such as any one or more of clay, kaolin, attapulgite, diatomaceous earth, waste glass powder, which has a pH of 7 or less or 7 as measured by a test paper method comprising immersing 10% of the agglomerated ashes in an aqueous solution at room temperature for 10 minutes, or tar which is a by-product of the "dry distillation" process defined in claim 1.
  4. 4. The "solid fuel product collection 1" as claimed in claim 1, wherein the ratio of the parts by weight W alkaline auxiliary material of the "alkali auxiliary material for preventing ashes from being sintered" as claimed in claim 3 to the parts by weight W Ashes of coal of the "A" or/and "B" or/and "C" or/and "D" ash as claimed in claim 1 is in the range of 0.1 to 0.25/1, the ratio of the parts by weight W Acid auxiliary material of the "acid auxiliary material" as claimed in claim 3 to the parts by weight W Ashes of coal of the "A" or/and "B" or/and "C" or/and "D" ash as claimed in claim 1 is in the range of 1 to 1.5/1, and the ratio of the parts by weight W Tar oil of the "tar" as claimed in claim 2 to the parts by weight W A Or (b) / And B Or (b) / And C Or (b) / And D of the "A" or/and "B" or/and "C" or/and "D" as claimed in claim 1 is in the range of 0 to 1.5/10.
  5. 5. The solid fuel product collection 1 of claim 1 is characterized in that the solid fuel is formed by drying and dehydrating the A or/and the B or/and the C or/and the D of claim 1 or the D, mixing the mixture with the W A /W B /W C /W D of claim 1 in the range of 0-9.9/0-5/0-10/0-6, extruding the mixed material through a hole die to form a columnar granular solid fuel or extruding the solid fuel into a solid or hollow bar solid fuel through the hole die; Or the solid fuel product collection 1 of claim 1 is characterized in that the solid fuel of the A or/and the B or/and the C or/and the D of claim 1 or the solid fuel and the solid fuel are dried and dehydrated, and after the solid fuel is mixed by the W A /W B /W C /W D of the claim 1 in the range of 0-9.9/0-5/0-10/0-6, the mixed material is treated by a honeycomb brick or honeycomb coal or coal ball or nonstandard extruder, and is pressed into a porous brick shape, honeycomb coal shape, coal ball shape or bending fruit shape, or a concave crack groove which is convenient for the subsequent ash to crush can be preset on the outer surface of the solid fuel.
  6. 6. The solid fuel product collection 1 of claim 1 relates to a porous brick-shaped solid fuel of claim 5, wherein the composition of the solid fuel contains an acidic auxiliary material F of claim 3, such as any one or more of clay, kaolin, attapulgite, kieselguhr and waste glass powder, which is used as a sintering material, or the percentage by weight W Acid auxiliary material of the acidic auxiliary material in the total weight of the solid fuel can be in the range of 10-20%.
  7. 7. The solid fuel product collection 1 of claim 1 wherein the physical properties of the composition, ash, and calorific value comprise a first combination of a, b, d, or preferably a, b, d, f, or a second combination of a, c, e, or preferably a, c, e, f, as follows: a. The composition is that under the framework that W A +W B +W C +W D is equal to 10 weight parts, W A /W B /W C /W D is changed from 0 to 9.9/0 to 5/0 to 10/0 to 6; b. The molar ratio of (SiO 2 +Al 2 O 3 ) mol/(CaO+MgO) mol in the ashes after combustion is less than 2, or the pH value is more than or equal to 8 by a test paper method of room temperature aqueous solution which contains 10% of ashes and is soaked for 10 minutes, and the combustion heat value is more than or equal to 2500 kilocalories/kg; c. The molar ratio of (SiO 2 +Al 2 O 3 ) mol/(CaO+MgO) mol in the ashes after combustion is more than or equal to 2, or the pH value is less than or equal to 7 or about 7 measured by a test paper method of room-temperature aqueous solution containing 10% of caking ashes after soaking for 10 minutes, and the combustion heat value is more than or equal to 2500 kilocalories/kg; d. Ash is in a loose state; e. the ash is in a sintering state with regular shape, and the 'regular shape' at least comprises a porous brick shape or a sphere-like/stone-like shape similar to the size of a quail egg; f. preferably, the combustion heat value is more than or equal to 4500 kilocalories/kg.
  8. 8. The "refined wood vinegar" of "subset 2" as defined in claim 1, characterized by the following first combination of 8-1, 8-3 and 8-4, or 8-1 to 8-4, "emulsified tar" of "subset 2" as defined in claim 1, characterized by the following second combination of 8-1, 8-2 and 8-5 and 8-6, or 8-1 and 8-5 and 8-6: 8-1. Raw materials for dry distillation are a combination of any one or more of the following plant materials: The method of claim 1, wherein the plant material comprises at least one or more of the combination of agricultural discarded straw/dried vine/seed husks, natural withering of road or woodland/landscaping or pruning discarded crotch; Or (b) The "B" of claim 1, at least comprising any one or more of food waste, kitchen waste, livestock and poultry manure, and mycelium fermentation residue discarded by biochemical industry; 8-2, or crushing the raw materials in the step 8-1 before the raw materials enter a carbonization tank for treatment, or adding any one or more of acid clay, kaolin, diatomite and glass powder, or extruding any one of granular, bar-shaped, spherical, mesoporous tubular and honeycomb brick materials as intermediate materials; 8-3, condensing and refluxing dry distillation smoke/gas through the top of a rectifying tower, removing smoke, collecting distillate with the temperature of the top of the tower in the range of 85-190 ℃, condensing, collecting by using a room temperature or low temperature temporary storage tank, or adsorbing and filtering to obtain detoxified refined wood vinegar; 8-4.8-3, wherein the pH of the 10% aqueous solution of the refined wood vinegar is in the range of 1 to 3, and the main harmful components are limited in the following ranges: according to national standard GB/T5009.27-2016, 3, 4-benzopyrene is less than 2 mug/kg, Detected according to national standard GB/T16631-2008, formaldehyde is less than 1mg/kg, Detected according to national standard GB/T15337-2008, lead is less than 1mg/kg, Detected according to national standard GB/T21191-2007, and arsenic is less than 0.1mg/kg; 8-5, condensing and refluxing dry distillation smoke/gas through a rectifying tower, falling into a reboiling tank below the rectifying tower, discharging tar in the reboiling tank which is controlled to be in a range of 210-250 ℃ at constant temperature after stopping collecting fractions above the 190 ℃ at the top of the tower, adding an emulsifying agent, controlling the pH value to be less than or equal to 7, adding an active carbon adsorbent or water under the condition that materials are not sticky, and filtering under the condition that the temperature is reduced to be below 100 ℃ and not sticky, thereby preparing detoxified plant dry distillation emulsified tar; 8-6.8-5, wherein the polycyclic aromatic hydrocarbon content in the emulsified tar is less than or equal to 50mg/L, and the volatile content therein meets the quality test that the mixed rubber compound/mixture is a material which is not subjected to the treatment process of the cracking temperature which can not be born by rubber, the mixed rubber compound/mixture can bear the non-fuming test of 180 ℃ per 10 minutes in a vulcanizing instrument or a mooney meter, the mixed rubber compound/mixture is that the weight content of the emulsified tar in the rubber compound/mixture with the pure rubber weight content of not less than 30 percent is in the range of 10 to 30 percent, the non-bearable cracking temperature is that the non-bearing temperature is not higher than or equal to 180 ℃ before, the non-fuming test specifically comprises the steps of taking 3-5 g of a rubber compound/mixture sample, respectively cushioning one polyester film on the sample, then placing the sample on the vulcanizing instrument or the mooney viscometer, heating the sample for 10 minutes at 180 ℃, taking out the sample, standing the sample at room temperature for not less than 5 minutes, then taking the polyester film at the room temperature, and transferring the upper and lower polyester film to the fluorescent lamp under the condition of not to the fluorescent lamp of the international standard of PAONC (PAC) and observing the yellow color of the sample or the PAC; The formula of the rubber compound/mixture comprises 100 parts of styrene-butadiene rubber, 5 parts of zinc oxide, 1 part of stearic acid, 2 parts of sulfur, 1.5 parts of accelerator CZ, 0.5 part of accelerator TMTD, 1 part of anti-aging agent MB, 330 to 60 parts of carbon black N, 0 to 200 parts of calcium carbonate, 0 to 15 parts of engine oil and a vulcanization condition of 155 ℃ per 7 minutes; any of the "refined pyroligneous liquor", "emulsified tar" described in the above 8-1 to 8-6 can be used as an independent product.
  9. 9. The "refined wood vinegar with a boiling range temperature of 85-190 ℃ under normal pressure" in claim 1, further comprising a fraction at least in the range of 85-190 ℃ and separated into low-temperature and high-temperature 2 sections for collection according to market requirements, wherein the two sections are: Low temperature section product A Low temperature section , such as 85-95 ℃, and high temperature section product A High temperature section , such as 95-190 ℃; Or a low-temperature section product A Low temperature section is 85-100 ℃ and a high-temperature section product A High temperature section is 100-190 ℃; Or a low-temperature section product A Low temperature section is 85-105 ℃ and a high-temperature section product A High temperature section is 105-190 ℃; Or a low-temperature section product A Low temperature section is 85-120 ℃ and a high-temperature section product A High temperature section is 120-190 ℃; Or a low-temperature section product A Low temperature section is 85-135 ℃ and a high-temperature section product A High temperature section is 135-190 ℃; Or a low-temperature section product A Low temperature section is 85-155 ℃ and a high-temperature section product A High temperature section is 155-190 ℃; the fraction can be divided into low, medium and high sections to be respectively collected according to market requirements at the temperature of 85-190 ℃, and the method comprises the following steps: Low temperature section product A Low temperature section , such as 85-95 ℃, medium temperature Duan Chanpin A intermediate temperature section , such as 95-125 ℃, and high temperature section product A High temperature section , such as 125-190 ℃; Or a low-temperature section product A Low temperature section , such as 85-100 ℃, a medium-temperature Duan Chanpin A intermediate temperature section , such as 100-135 ℃, and a high-temperature section product A High temperature section , such as 135-190 ℃; Or low temperature section product A Low temperature section , such as 85-105 ℃, medium temperature Duan Chanpin A intermediate temperature section , such as 105-140 ℃, and high temperature section product A High temperature section , such as 140-190 ℃; Or low temperature section product A Low temperature section , such as 85-120 ℃, medium temperature Duan Chanpin A intermediate temperature section , such as 120-155 ℃, and high temperature section product A High temperature section , such as 155-190 ℃; Or low temperature section product A Low temperature section , such as 85-135 ℃, medium temperature Duan Chanpin A intermediate temperature section , such as 135-155 ℃, and high temperature section product A High temperature section , such as 155-190 ℃; Or low temperature section product A Low temperature section , such as 85-155 ℃, medium temperature Duan Chanpin A intermediate temperature section , such as 155-165 ℃, and high temperature section product A High temperature section , such as 165-190 ℃; The product A Low temperature section 、A High temperature section divided into low, high temperature 2 sections or the product A Low temperature section 、A intermediate temperature section 、A High temperature section divided into low, medium and high temperature 3 sections can be made into independent products.
  10. 10. The "emulsified tar" as set forth in claim 1, which has a 10% aqueous pH, preferably in the range of 6 to 7.
  11. 11. The method of claim 1, wherein the "subset 1" comprises at least a combination of the following steps: Step I, preparing materials, namely, preparing main/auxiliary materials capable of being granulated or pressed into solid fuel by adopting a self-made or/and market purchase or proxy substitution mode: The main material comprises: selecting a preparation material according to the items "A", "B", "C", "D" in claim 1 or 2, or drying and dehydrating the preparation material; Auxiliary materials, namely selecting materials which are prepared according to the alkaline auxiliary materials, the acidic auxiliary materials and the tar in the claim 3; Step II, according to the description of claim 1, "W A /W B /W C /W D is in the range of 0-9.9/0-5/0-10/0-6", and according to the description of claim 4, "W alkaline auxiliary material /W Ashes of coal is in the range of 0.1-0.25/1", "W Acid auxiliary material /W Ashes of coal is in the range of 1-1.5/1", "W Tar oil /W A Or (b) / And B Or (b) / And C Or (b) / And D is in the range of 0-1/10", and according to the description of claim 6, "the weight percentage of the 'acidic auxiliary material' in the total weight of the 'solid fuel' W Acid auxiliary material % can be in the range of 10-20%"; Step III, according to the method of claim 5, the granular solid fuel which is extruded through the hole die to form a bar shape or the bar solid fuel which is extruded through the hole die to form a solid or hollow bar shape, or the extrusion machine is used for forming honeycomb bricks or honeycomb coal or briquettes or nonstandard extrusion machines; And IV, metering and packaging, or stacking on a logistics tray and warehousing.
  12. 12. The method of claim 1, further comprising preparing a first composition wherein "refined wood vinegar" is used in subset 2 using steps 12-1 to 12-5, and for "emulsified tar" is used in subset 2 using a second composition wherein steps 12-1, 12-2 and 12-5, 12-6 are used, and for "C" is used in subset 1 using a third composition wherein steps 12-1, 12-2 and 12-7 or 12-8 are used: Preparing materials, namely, taking the 'A' or/and the 'B' defined in the claims 1 and 2 as raw materials for carbonization, crushing the raw materials before the raw materials are processed in a carbonization tank, or removing stone/iron hard impurities, or drying the raw materials, or adding an intermediate material 1 of any one or a plurality of acid clay, kaolin, diatomite and glass powder, or extruding the intermediate material 1 into any one of a granular shape, a rod shape, a medium-hole tube shape and a honeycomb brick shape as an intermediate material 2, or taking the 'crotch' in the 'A' defined in the claims 1 and 2 as raw materials, and crushing the raw materials before the raw materials are processed in the carbonization tank, or cutting the raw materials into the raw materials which meet the market demands and include the range of 10-20 cm, so as to obtain an intermediate material 3; 12-2, feeding the intermediate material 1 or the intermediate material 2 or the intermediate material 3 in the step 12-1 into a carbonization tank, wherein the carbonization tank can be heated by using combustible gas, and the heating speed in the carbonization tank is controlled to be in the range of 3-5 ℃ per minute; 12-3, using a rectifying tower with a heating reboiling tank at the bottom, condensing and refluxing the smoke/gas slowly output from the dry distillation tank through the top of the rectifying tower, or collecting fractions with the distillation temperature of 85-190 ℃ under the normal pressure at the top of the tower after smoke elimination, wherein the "fractions with the distillation temperature of 85-190 ℃ under the normal pressure" can be divided into low-temperature and high-temperature 2 sections or low-temperature, medium-temperature and high-temperature 3 sections according to claim 9 or 10 at least, and respectively collected; 12-4, condensing and standing the distillate with the overhead temperature of 85-190 ℃ under normal pressure in the section 12-3, or carrying out active carbon adsorption and filtration on the distillate with the overhead temperature of 85-190 ℃ respectively collected and higher than 100 ℃, thereby preparing purified wood vinegar with impurity removal of the distillate with the overhead temperature of 85-190 ℃ under normal pressure; 12-5, introducing the gas which is not condensed into liquid after passing through a condenser and is not condensed into the liquid under the normal pressure and the distillation temperature of the top of the tower is in the range of 85-190 ℃ in 12-3 into the combustible gas pipeline in 12-2 for being used as the fuel gas of a heating stove of a carbonization tank system; 12-6, condensing and refluxing dry distillation smoke/gas through a rectifying tower, falling into a reboiling tank below the rectifying tower, discharging tar which is controlled to be in a range of 210-250 ℃ at constant temperature in the reboiling tank after the distillation at the temperature of more than 190 ℃ is stopped collecting at the top of the tower, adding an emulsifying agent, controlling the pH value to be less than or equal to 7, adding an active carbon adsorbent or water under the condition that the materials are not sticky, and filtering to obtain the decontaminated emulsified tar, wherein the emulsifying agent can be any one or a combination of a plurality of nonionic surfactants or anionic surfactants; For the dry distillation tank, an intermittent static tank is used, preferably, the intermediate material 2 or the intermediate material 3 is put into the tank, when the temperature in the tank is increased to 450 ℃ or higher and no great amount of smoke/gas is distilled, the dry distillation tank can be cooled, and the tank is opened to take out any solid carbon in the shape of granules, bars, medium pore tubes, honeycomb bricks or natural tree weight short sections after the temperature is reduced to the temperature without choking smell when the tank is opened, such as below 50 ℃, namely, the carbon residue after dry distillation of the A or/and B in claim 1; For the dry distillation tank, a continuous dynamic tank is used, preferably the intermediate material 1 is used as described in the previous 12-1, when the temperature of a moving material section in the tank has risen to 450 ℃ or higher and no great amount of smoke/gas is distilled, the material section can be gradually moved and cooled, and the material section is cooled to a discharging temperature without choking smell, such as below 50 ℃, and dry distillation carbon residue in a powder dust form in the tank is discharged.
  13. 13. The clean production method of the method attached to the claim 11 and 12 is characterized in that a production line device for executing the preparation process method is arranged in a group of containers with at least auxiliary functions of silencing, dedusting and convenient maintenance/moving, the production line can be used for producing a set of clean products combined in different series/specifications by taking the combustible garbage including continuously generated dead branches/straws, excrement/household garbage and waste plastic films in the environment as raw materials through different combinations of containers with the process functions of fermentation/crushing, impurity removal, drying, mixing, granulating, packaging, carbonization, rectification, condensation, buffer storage, adsorption, filtration and filling.
  14. 14. The use of "subset 1", "subset 2" as defined in claim 1, in particular for "subset 1" comprising at least the following 14-1 and 14-2, in terms of the characteristics of the "fuel" ashes therein, and for "subset 2" comprising at least the following 14-3 to 14-5, the "crude pyroligneous", "refined pyroligneous", "dehybridized emulsified tar" therein: The use of solid fuel characterized by the ash of claim 7, wherein the ash is used for combustion power generation or steam heating or for lime burning, at least with perfect tail gas dust removal; The use of the solid fuel characterized by the "c" ash according to claim 7, at least widely used as a heating solid fuel in a house or an agricultural greenhouse, and the use of the "c" characterized solid fuel ash as brick, stone, sand material in building materials, or as ingredients for baking-free bricks, baking-free tiles, or as slow-release granular fertilizers for inorganic nutrient elements in plant cultivation; 14-3 using the "crude pyroligneous liquor" of claim 1 as a raw material for preparing a refined pyroligneous liquor for sale or self-use in the market; 14-4, the refined wood vinegar can be used as an insecticidal/sterilizing agent or a compounding ingredient of the insecticidal/sterilizing agent in agriculture, can be used as plant growth hormone or page fertilizer, can also be used as a deodorizing/sterilizing agent for raising pets or livestock houses or for deodorizing garbage transportation and cadaver treatment sites; 14-4. The "dehazing emulsified tar" according to claim 1 can be used at least as a softener component in rubber formulation.
  15. 15. The "collection of cleaning products" of claim 1 and the "method of manufacture" of claims 11 to 13 or the "method of cleaning production" of its attachments, the use of which may comprise at least any one or more of the following combinations: 15-1, can be connected in the industrial parks of the current printing and packaging industry to help absorb the plastic-containing waste selvedge out-road obstruction of the printing and packaging products in the industrial parks; 15-2, or is connected with the current production device for preparing organic fertilizer by treating wet household garbage so as to help absorb the 'organic fertilizer' stagnation obstruction existing in the enterprises; 15-3, or is connected after the current waste paper pulping production device to help to eliminate the waste plastic film material outlet obstruction of the enterprises; 15-4, or is connected after the current garbage sorting production device to help to eliminate the waste plastic out of the road stem cations existing in the enterprises; 15-5, or is set up in the landfill region, in order to prevent the expansion potential of the landfill, and lay the industrial foundation for eliminating the landfill finally; 15-6, or be set up in the forest farm, in order to help the forest farm to consume the dry branches/leaves that are produced in the forest land, and consume the dry/wet domestic waste that resident's life produces; 15-7, or is arranged near the domestic sewage purifying sedimentation tank to help the domestic sewage purifying industry to utilize the green high-value resources of the combustible sedimentary sludge discharged by the domestic sewage purifying industry; 15-8, or is arranged near the fermentation process device of the biochemical industry to help the biochemical industry to consume the discarded mycelium fermentation residues.

Description

Cleaning product collection prepared from environmental waste Technical Field The invention provides a clean product collection prepared from environmental garbage, which comprises a solid fuel product subset 1, or a coarse pyroligneous liquor, or/and refined pyroligneous liquor, or a de-mixed emulsified tar product subset 2, wherein the subset 1 is at least formed by combining any one of four A, B, C, D materials with any one or more of the other three materials, and the A, B, C, D specifically comprises A, namely biomass garbage materials in an environment which are not or hardly odorous, B, namely biomass garbage fermented materials in a deodorized and disinfected environment, C, namely carbon residues left after carbonization of at least the A or/and the B, and D, namely waste plastics in the environmental garbage or/and waste plastics purchased commercially. The invention belongs to the field of harmless utilization of garbage resources. Background The current quantitative disposal modes of the environmental garbage mainly comprise landfill, incineration and fertilizer preparation. The environmental refuse landfill has the defects that a large amount of land is occupied, underground water, soil, air and the like are polluted, and the cost for repairing the land after the refuse landfill is extremely high, so that the method is an inequality strategy for polluting the current generation and endangering the offspring. The method has the advantages that even if the tail gas emission of the garbage can reach the new national standard of European standard (GB 18485-2014) on the control standard of domestic garbage incineration, the heat energy of the combustion furnace is generally not paid attention to high-value utilization due to the smaller treatment capacity of the combustion furnace, the output/input ratio is generally lower, the garbage is subjected to harmless incineration power generation due to the fact that the low-temperature gasification furnace is used for collecting the environmental garbage in a larger range in a county and municipal scale, the current situation of China generally adopts dry domestic garbage collected from society as solid fuel, has the advantages of improving the power generation, but has potential harmful effects on the environment garbage, is not harmful to the state of the prior art, and is harmless to the current state of the garbage, and is not harmful to the environment. The organic fertilizer prepared by the fermentation process has the defects that at least more micro plastics or/and inorganic salts exist, and the organic fertilizer is continuously applied to small fields such as greenhouse vegetables, orchards, parks, forest lands and the like which are economically seemingly unimpeded at present by the organic hypertrophy amount because of the large use of wet wastes including kitchen wastes, catering wastes and kitchen wastes or/and livestock manure fed with compound feeds doped with inorganic salts such as ferrous sulfate, copper sulfate, zinc sulfate, manganese sulfate and the like. The method mainly comprises the steps of landfill, incineration and fertilizer preparation for the environmental garbage. The landfill has the defects of occupying a large amount of land and polluting the environment, and the land repair cost of the landfill is extremely high, which is an inequality strategy for polluting the contemporary hazard offspring. The method has the defects that the waste is simply scattered and incinerated in the open air, which brings about a large number of pollution including dioxin, polycyclic aromatic hydrocarbon harmful smoke dust and the like, the waste is subjected to harmless incineration by adopting a low-temperature gasifier in a village and town area, the waste is subjected to harmless incineration by adopting a small-range collection method, but the heat energy of the combustion furnace is generally not paid attention to high-value utilization due to small treatment capacity of the combustion furnace, so that the output/input ratio is generally low, the waste is subjected to harmless incineration power generation by adopting a low-temperature gasifier in a large-range collection method in a county and city area, the current domestic situation is that the burnt waste is generally subjected to harmless incineration power generation by adopting dry domestic waste collected from society as solid fuel, so that wet waste cannot be treated in view of the upper-level requirement of the waste to be treated with high benefit, and the ash generated by the incineration method is disordered and potential hazard caused by the treatment of the ash generated by the incineration method at present due to the novel theory of harmful state and harmless state conversion of the polycyclic aromatic hydrocarbon. The fertilizer has the disadvantages that inorganic salt and more waste plastics exist in wet garbage, and the organic fertilizer is applied to fields contin