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CN-122003172-A - Herbicide/safener combinations based on substituted [ (1, 5-diphenyl-1H-1, 2, 4-triazol-3-yl) oxy ] acetic acid safeners and substituted cyclodione herbicides and salts thereof

CN122003172ACN 122003172 ACN122003172 ACN 122003172ACN-122003172-A

Abstract

The present application relates to a combination comprising one or more active components (a) as safeners and one or more herbicidally active compounds (component (B)), wherein component (a) represents one or more compounds of the general formula (I) or an agrochemically acceptable salt thereof and component (B) represents one or more herbicides. The application also relates to a method or use of the safener/herbicide combinations according to the application for controlling harmful plants or for regulating growth.

Inventors

  • J. Frankenborough
  • H. Helmk
  • E. Asmas
  • H. ARENS
  • S. Lyle
  • T. MUELLER

Assignees

  • 拜耳公司

Dates

Publication Date
20260508
Application Date
20240704
Priority Date
20230821

Claims (15)

  1. 1. A herbicide/safener combination comprising one or more compounds (A) and one or more herbicidally active compounds (B), wherein (A) represents one or more compounds of the formula (I) or an agrochemically acceptable salt thereof, And wherein the first and second heat sinks are disposed, (R a ) p -phenyl represents a group Q-1.1 to Q-1.55: and (R b ) q -phenyl represents a group Q-2.1 to Q-2.55: R c is hydrogen, and the hydrogen atom, And R d is hydrogen, methyl, ethyl, n-propyl, isopropyl, n-butyl, n-pentyl, phenyl, benzyl, CH 2 (4-Cl-Ph)、CH 2 (4-F-Ph)、CH 2 (4-OMe-Ph), 2-methoxyethyl, tetrahydrofuran-2-yl-methyl, tetrahydrofuran-3-yl-methyl, tetrahydropyran-2-ylmethyl, tetrahydropyran-3-ylmethyl, tetrahydropyran-4-ylmethyl, methylpropan-3-yl, ethylpropionate-3-yl, methylacetate-2-yl, ethylacetate-2-yl, methylpentanoate-2-yl, ethylpivalate-3-yl, methyl-2-methylpropanoate-3-yl, methyl-2, 2-dimethylpropionate-3-yl, ethyl-2-methylpropanoate-3-yl, methyl-2-propionate-2-yl, ethyl-2-propionate-2-yl, ethylacetate-2-yl, methyl-1-methylcyclopropane-2-yl, ethylacetate-1-methylpropanoate-2-yl, ethylcyclopropane-2-yl, ethylformate-2-oxo-2, 3-fluoro-2, 3-fluoro-ethyl, 3-methylpropanoate-2-yl, fluoro-2-ethyl, 3-methylpropanoate, cyclopropylmethyl, 1-cyclopropyl-ethyl, (1-methylcyclopropyl) methyl, (2, 2-dichlorocyclopropyl) methyl, (2, 2-dimethylcyclopropyl) methyl, allyl, propargyl (prop-2-yn-1-yl), 2-chloroprop-2-en-1-yl, 3-phenylprop-2-yn-1-yl, 3-dichloroprop-2-en-1-yl, 3-dichloro-2-fluoroprop-2-en-1-yl, methylpropp-2-yn-1-yl, 2-methylpropp-2-en-1-yl but-2-en-1-yl, but-3-en-1-yl, but-2-yn-1-yl, but-3-yn-1-yl, 4-chlorobbut-2-yn-1-yl, 3-methylbutan-2-en-1-yl, 3-methylbutan-1-en-1-yl, 1- (2E) -1-methylbutan-2-en-1-yl, (E) -pent-3-en-2-yl or (Z) -pent-3-en-2-yl, cyclobutylmethyl, cyclopentylmethyl, cyclohexylmethyl, heptan-2-yl, isobutyl, 1, 3-dioxolan-2-ylmethyl or 1-ethyl-5-methyl-1H-pyrazol-4-methyl, And (B) Represents one or more compounds of the general formula (II) or an agrochemically acceptable salt thereof, Wherein the method comprises the steps of Q is selected from Q-1、Q-2、Q-3、Q-4、Q-5、Q-6、Q-7、Q-8、Q-9、Q-10、Q-11、Q-12、Q-13、Q-14、Q-15、Q-16、Q-17、Q-18、Q-19、Q-20、Q-21、Q-22、Q-23、Q-24、Q-25、Q-26、Q-27、Q-28、Q-29、Q-30、Q-31 and Q-32, Wherein said arrow is Representing the bond of a carbon atom to a Z group, dotted line Representing the bond of a carbon atom to a W group; R 1 is methyl, ethynyl, 1-propynyl, phenyl or a five-or six-membered heteroaromatic ring containing one or two nitrogen atoms, wherein the phenyl ring and the heteroaromatic ring may be substituted by one or two R 9 groups, R 2 is chloro, (C 1 -C 3 ) -alkoxy, (C 1 -C 2 ) -alkoxy- (C 1 -C 3 ) -alkoxy, (C 1 -C 2 ) -fluoroalkoxy, methyl, ethyl, n-propyl, n-butyl, cyclopropyl or ethynyl, R 3 is hydrogen, fluorine, chlorine, bromine, methyl, ethyl, n-propyl, cyclopropyl, vinyl, ethynyl, (C 1 -C 3 ) -alkoxy, (C 1 -C 3 ) -fluoroalkyl, (C 1 -C 2 ) -fluoroalkoxy, (C 1 -C 2 ) -alkoxy- (C 1 -C 3 ) -alkoxy or C 1 -fluoroalkoxy- (C 1 -C 3 ) -alkoxy, W is a bond, CR 4 R 5 , O, NH or N-CH 3 , Z is a bond, CR 6 R 7 , O, NH or N-CH 3 , Provided that W and Z cannot be both a bond, Y is O or N-R 8 , N1 and n2 are independently 0,1, 2 or 3, provided that n1+n2=2, 3, 4, 5 or 6, R 1Q3 is hydrogen, (C 1 -C 6 ) -alkyl, (C 1 -C 6 ) -haloalkyl, (C 1 -C 6 ) -alkoxy- (C 1 -C 3 ) -alkyl or (C 1 -C 6 ) -haloalkoxy- (C 1 -C 3 ) -alkyl, R 2Q3 is- (CH 2 ) k -R 3Q3 ), Wherein R 3Q3 is selected from the group consisting of-C (O) NR 5N R 6N 、-NR 5N R 6N and-S (O) 2 NR 16N R 17N , And k is 0, 1 or 2, Or R 1Q3 and R 2Q3 together are- (CH 2 ) nq1 -C(R 4Q3 )R 5Q3 -(CH 2 ) nq2 ) -in which nq1 and nq2 are independently 1 or 2, R 4Q3 is hydrogen, (C 1 -C 6 ) -alkyl, hydroxy, methoxy or halogen, R 5Q3 is selected from the group consisting of-C (O) NR 5N R 6N 、-NR 5N R 6N and-S (O) 2 NR 16N R 17N , Or R 4Q3 and R 5Q3 together are- (CH 2 ) nq3 -N(R 8 )-(CH 2 ) nq4 ) -in which nq3 and nq4 are independently 1 or 2, R 1Q10 and R 2Q10 are independently selected from hydrogen, halogen, (C 1 -C 3 ) -alkyl, (C 1 -C 3 ) -haloalkyl and (C 1 -C 3 ) -alkoxy, Y p is selected from O, CR Y1 R Y2 and N-R Y3 , Wherein R Y1 is hydrogen or (C 1 -C 4 ) alkyl, R Y2 is hydrogen or (C 1 -C 4 ) alkyl, and R Y3 is selected from hydrogen, (C 1 -C 4 ) -alkyl, (C 1 -C 4 ) -alkoxy, (C 1 -C 4 ) -haloalkyl, - (CO) (C 1 -C 4 ) -alkyl and- (CO) (C 1 -C 4 ) -haloalkyl; Y q is N or CH, and the total number of the N or CH, R 4 、R 5 、R 6 and R 7 are each independently hydrogen, (C 1 -C 5 ) -alkyl, (C 2 -C 4 ) -alkenyl, (C 2 -C 4 ) -alkynyl, (C 1 -C 2 ) -fluoroalkyl, (C 1 -C 3 ) -alkoxy- (C 1 -C 3 ) -alkyl, (C 1 -C 3 ) -alkylthio- (C 1 -C 3 ) -alkyl, (C 1 -C 3 ) -alkylsulfinyl- (C 1 -C 3 ) -alkyl, (C 1 -C 3 ) -alkylsulfonyl- (C 1 -C 3 ) -alkyl, (C 3 -C 4 ) -cycloalkyl, or an unsubstituted 4-, 5-or 6-membered monocyclic heterocycle which carries a ring heteroatom selected from oxygen, sulfur or nitrogen and is attached to a ring carbon atom within the heterocyclic group, provided that no more than one of the R 4 、R 5 、R 6 and R 7 groups is alkenyl, alkynyl, alkoxyalkyl, alkylthioalkyl, alkylsulfinylalkyl, alkylsulfonylalkyl, cycloalkyl or heterocyclyl, Or R 4 and R 5 together form a- (CH 2 ) n3 -or- (CH 2 ) n4 -X 1 -(CH 2 ) n5 -group) and R 6 and R 7 are as defined above, Or R 6 and R 7 together form a- (CH 2 ) n3 -or- (CH 2 ) n4 -X 1 -(CH 2 ) n5 -group) and R 4 and R 5 are as defined above, Wherein X 1 is O (oxygen), S (sulfur), S (O) 2 、N(R 8 )、C(H)((C 1 -C 2 ) -alkyl, C ((C 1 -C 2 ) -alkyl) 2 or C (H) ((C 1 -C 2 ) -alkoxy); n3 is 2, 3, 4 or 5, N4 and n5 are independently 1, 2 or 3, provided that n4+n5=2, 3 or 4, Or R 5 and R 6 together form- (CH 2 ) n6 -or a- (CH 2 ) n7 -C(R 10a )(R 10b )-(CH 2 ) n8 -or-C (R 10c )=C(R 10d ) -group, wherein R 10a is (C 1 -C 2 ) -alkyl or (C 1 -C 2 ) -alkoxy; and R 10b is hydrogen or (C 1 -C 2 ) -alkyl, provided that when R 10a is (C 1 -C 2 ) -alkoxy, R 10b is hydrogen, and wherein n6 is 1,2 or 3, n7 and n8 are independently 0, 1 or 2, provided that n7+n8=0, 1 or 2, and wherein R 10c and R 10d are independently hydrogen or (C 1 -C 2 ) -alkyl, R 8 is hydrogen, (C 1 -C 4 ) -alkyl, (C 1 -C 4 ) -alkoxy, (C 1 -C 4 ) -haloalkyl, -C (O) (C 1 -C 4 ) -alkyl, -C (O) (C 1 -C 4 ) -haloalkyl, -S (O) n (C 1 -C 6 ) -alkyl, -S (O) n (C 1 -C 6 ) -haloalkyl, -S (O) n -(CH 2 ) n -(C 3 -C 6 ) -cycloalkyl 、-S(O) n C(R 11N )R 12N R 13N 、-C(O)H、-C(O)-(CH 2 ) n -(C 3 -C 6 )- cycloalkyl, -C (O) C (R 11N )R 12N R 13N 、-C(O)(C 2 -C 4 ) -alkenyl ,-C(O)(CR 9N R 10N )CN、-C(O)(CR 9N R 10N )(CR 9N R 10N )CN、-C(O)CH 2 C(O)-(C 1 -C 6 )- alkyl, -C (O) CH 2 OC(O)-(C 1 -C 6 ) -alkyl, -C (O) O (C 1 -C 6 ) -alkyl, -C (O) O (C 1 -C 6 ) -haloalkyl, -C (O) (CH 2 ) n S(O) n (C 1 -C 6 ) -alkyl, -C (O) (C 1 -C 3 ) -alkoxy- (C 1 -C 6 ) -alkyl, -C (O) (C 1 -C 3 ) -alkoxy- (C 2 -C 6 ) -alkenyl, -C (O) (C 1 -C 3 ) -alkoxy- (C 2 -C 6 ) -alkynyl, -C (O) (C 1 -C 3 ) -alkoxy- (C 1 -C 6 ) -haloalkyl, -C (O) (C 1 -C 3 ) -alkoxy- (C 3 -C 6 ) -cycloalkyl, -C (O) O (C 1 -C 3 ) -alkoxy- (C 1 -C 6 ) -alkyl, -C (O) (C 1 -C 3 ) -alkoxy- (C 1 -C 3 ) -alkoxy- (C 1 -C 6 ) -alkyl 、-C(O)(CH 2 ) n NR 5N R 6N 、-C(O)-(CH 2 ) n -NR 7N C(O)R 8N 、-C(O)-(CH 2 ) n -ON=CR 5N R 5N 、-CN、-S(O) 2 NR 16N R1 7N 、-S(O)(=NR 18N )R 19N 、-C(O)C(O)R 20N 、-C(O)C(R 23N )=NOR 24N 、-C(O)C(R 23N )=N-NR 25N R 26N 、-(CH 2 ) n - phenyl, -C (O) - (CH 2 ) n -phenyl, -S (O) n -(CH 2 ) n -phenyl, heterocyclyl, -C (O) - (CH 2 ) n -heterocyclyl, -C (O) (CH 2 ) n -O-(CH 2 ) n -heterocyclyl), -S (O) n -(CH 2 ) n -heterocyclyl, wherein each heterocyclyl is a five-or six-membered heterocyclyl ring, which may be aromatic, saturated or partially saturated, and may contain one to four heteroatoms, wherein each heteroatom is independently selected from oxygen, nitrogen and sulfur, and wherein the heterocyclyl ring or benzene ring may optionally be substituted with one, two or three substituents independently selected from (C 1 -C 3 ) -alkyl, (C 1 -C 3 ) -haloalkyl, (C 1 -C 3 ) -alkoxy, (C 2 -C 3 ) -alkenyl, (C 2 -C 3 ) -alkynyl, Substituents for halogen, cyano and nitro; R 9 represents a substituent independently selected from (C 1 -C 4 ) -alkyl, (C 1 -C 4 ) -haloalkyl, cyano and halogen; R 5N represents a substituent independently selected from hydrogen and (C 1 -C 6 ) -alkyl, R 6N represents a member independently selected from hydrogen, (C 1 -C 6 ) -alkyl, (C 2 -C 6 ) -alkenyl, (C 2 -C 6 ) -alkynyl, (C 1 -C 6 ) -haloalkyl, hydroxy, (C 1 -C 6 ) -alkoxy, (C 3 -C 6 ) -cycloalkyl, - (C 1 -C 4 ) -alkoxy- (C 1 -C 6 ) -alkyl, - (C 1 -C 3 ) -alkoxy- (C 1 -C 6 ) -haloalkyl, - (CR 9N R 10N )-(C 1 -C 6 ) -haloalkyl 、-(CR 9N R 10N )C(O)NR 5N R 5N 、-C(O)H、-C(O)-(CH 2 ) n -(C 3 -C 6 )- cycloalkyl, -C (O) - (CH 2 ) n -C(R 11N )R 12N R 13N , phenyl, pyridinyl substituents, wherein the phenyl ring and the pyridinyl ring are optionally substituted with one, two or three substituents independently selected from (C 1 -C 3 ) -alkyl, (C 1 -C 3 ) -haloalkyl, (C 1 -C 3 ) -alkoxy, (C 2 -C 3 ) -alkenyl, (C 2 -C 3 ) -alkynyl, halogen, cyano and nitro substituents, or R 5N and R 6N together form-CH 2 CH 2 OCH 2 CH 2 -, and R 7N is selected from hydrogen and (C 1 -C 6 ) -alkyl; R 8N is selected from hydrogen, (C 1 -C 6 ) -alkyl, (C 1 -C 6 ) -alkoxy, (C 3 -C 6 ) -cycloalkyl, phenyl, pyridinyl, wherein the phenyl ring and the pyridinyl ring are optionally substituted with 1, 2 or 3 substituents independently selected from (C 1 -C 3 ) -alkyl, (C 1 -C 3 ) -haloalkyl, (C 1 -C 3 ) -alkoxy, (C 2 -C 3 ) -alkenyl, (C 2 -C 3 ) -alkynyl, halogen, cyano and nitro; r 9N is hydrogen or methyl; R 10N is hydrogen or methyl, or R 9N and R 10N together form-CH 2 CH 2 -, and R 11N is hydrogen or methyl; r 12N is selected from hydrogen, (C 1 -C 6 ) -alkyl, hydroxy, and (C 1 -C 6 ) -alkoxy; R 13N is selected from hydrogen, (C 1 -C 6 ) -alkyl, hydroxy and (C 1 -C 6 ) -alkoxy, or R 12N and R 13N together form-CH 2 -X-CH 2 -, and X is selected from O, S and N-R 14N ; R 14N is selected from hydrogen, (C 1 -C 3 ) -alkyl and (C 1 -C 3 ) -alkoxy; R 16N is hydrogen or (C 1 -C 6 ) -alkyl, and R 17N is selected from hydrogen, (C 1 -C 6 ) -alkyl, (C 3 -C 6 ) -cycloalkyl, (C 1 -C 6 ) -alkoxy- (C 1 -C 3 ) -alkyl, -C (O) (C 1 -C 6 ) -alkyl, -C (O) O (C 1 -C 6 ) -alkyl and CH 2 CN, or R 16N and R 17N together form -CH 2 CH 2 OCH 2 CH 2 -、-CH 2 CH 2 S(O) 2 CH 2 CH 2 -; R 18N is hydrogen or (C 1 -C 6 ) -alkyl; R 19N is selected from hydrogen, (C 1 -C 6 ) -alkyl, (C 1 -C 6 ) -alkoxy, (C 3 -C 6 ) -cycloalkyl, phenyl, pyridinyl, wherein the phenyl ring and the pyridinyl ring are optionally substituted with 1, 2 or 3 substituents independently selected from (C 1 -C 3 ) -alkyl, (C 1 -C 3 ) -haloalkyl, (C 1 -C 3 ) -alkoxy, (C 2 -C 3 ) -alkenyl, (C 2 -C 3 ) -alkynyl, halogen, cyano and nitro; R 20N is selected from (C 1 -C 6 ) -alkyl, (C 1 -C 6 ) -haloalkyl, (C 1 -C 6 ) -alkoxy, (C 1 -C 6 ) -haloalkoxy, -NR 21N R 22N , phenyl, pyridinyl, wherein the phenyl ring and the pyridinyl ring may be optionally substituted with 1,2, or 3 substituents independently selected from (C 1 -C 3 ) -alkyl, (C 1 -C 3 ) -haloalkyl, (C 1 -C 3 ) -alkoxy, (C 2 -C 3 ) -alkenyl, (C 2 -C 3 ) -alkynyl, halogen, cyano, and nitro; r 21N is selected from hydrogen, (C 1 -C 6 ) -alkyl, (C 1 -C 6 ) -alkoxy, (C 1 -C 6 ) -alkoxy- (C 1 -C 3 ) -alkyl, (C 3 -C 6 ) -cycloalkyl, (C 1 -C 6 ) -haloalkyl and (C 1 -C 6 ) -haloalkoxy, -C (O) (C 1 -C 6 ) -alkyl, phenyl, pyridinyl, wherein the phenyl ring and the pyridinyl ring may be optionally substituted with 1,2 or 3 substituents independently selected from (C 1 -C 3 ) -alkyl, (C 1 -C 3 ) -haloalkyl, (C 1 -C 3 ) -alkoxy, (C 2 -C 3 ) -alkenyl, (C 2 -C 3 ) -alkynyl, halogen, cyano and nitro; R 22N is hydrogen or (C 1 -C 6 ) -alkyl, or R 21N and R 22N together form-CH 2 CH 2 OCH 2 CH 2 -; R 23N is selected from hydrogen, (C 1 -C 6 ) -alkyl, (C 1 -C 6 ) -haloalkyl, (C 1 -C 6 ) -alkoxy, (C 1 -C 6 ) -haloalkoxy; R 24N is selected from hydrogen, (C 1 -C 6 ) -alkyl, (C 1 -C 6 ) -alkoxy- (C 1 -C 3 ) -alkyl, (C 3 -C 6 ) -cycloalkyl, -CH 2 CN, tetrahydropyranyl, phenyl, pyridinyl, wherein the phenyl ring and the pyridinyl ring may be optionally substituted with 1,2 or 3 substituents independently selected from (C 1 -C 3 ) -alkyl, (C 1 -C 3 ) -haloalkyl, (C 1 -C 3 ) -alkoxy, (C 2 -C 3 ) -alkenyl, (C 2 -C 3 ) -alkynyl, halogen, cyano and nitro; R 25N is hydrogen or (C 1 -C 6 ) -alkyl; r 26N is hydrogen or (C 1 -C 6 ) -alkyl; n is independently 0,1 or 2; G is hydrogen, an agrochemically acceptable metal, an agrochemically acceptable sulfonium group, an agrochemically acceptable ammonium group 、C(X 3 )-R 14 、-C(X 4 )-X 5 -R 15 、-C(X 6 )-N(R 16 )-R 17 、-SO 2 -R 18 、-P(X 7 )(R 19 )-R 20 、-CH 2 -X 8 -R 21 、(C 1 -C 6 )- alkoxy-C (O) -CH 2 -、(C 1 -C 6 ) -alkoxy-C (O) -CH=CH-, (C 2 -C 7 ) -en-1-yl-CH 2 -、(C 2 -C 7 ) -en-1-yl-CH [ (C 1 -C 2 ) -alkyl ] -, (C 2 -C 4 ) -fluoroalken-1-yl-CH 2 -、(C 2 -C 7 ) -alkyn-1-yl-CH 2 -、(C 2 -C 7 ) -alkyn-1-yl-CH [ (C 1 -C 2 ) -alkyl ] -, heteroaryl-CH 2 -, heteroaryl-CH [ (C 1 -C 2 ) -alkyl ] -, phenyl-CH 2 -, phenyl-CH [ (C 1 -C 2 ) -alkyl ] -, phenyl-C (O) -CH 2 -groups, where the phenyl or heteroaryl groups can optionally also be substituted independently by 1, 2 or 3 groups selected from (C 1 -C 2 ) -alkyl, C 1 -fluoroalkyl, (C 1 -C 2 ) -alkoxy, c 1 -fluoroalkoxy, fluoro, chloro, bromo, cyano, nitro, X 3 、X 4 、X 5 、X 6 、X 7 and X 8 are independently O (oxygen) and S (sulfur), R 14 is hydrogen, (C 1 -C 21 ) -alkyl, (C 2 -C 21 ) -alkenyl, (C 2 -C 18 ) -alkynyl, (C 1 -C 10 ) -fluoroalkyl, (C 1 -C 10 ) -cyanoalkyl, (C 1 -C 10 ) -nitroalkyl, (C 1 -C 10 ) -aminoalkyl, (C 1 -C 5 ) -alkylamino (C 1 -C 5 ) -alkyl, (C 2 -C 8 ) -dialkylamino (C 1 -C 5 ) -alkyl, (C 3 -C 7 ) -cycloalkyl- (C 1 -C 5 ) -alkyl, (C 1 -C 5 ) -alkoxy- (C 1 -C 5 ) -alkyl, (C 3 -C 5 ) -alkenyloxy- (C 1 -C 5 ) -alkyl, (C 3 -C 5 ) -alkynyloxy- (C 1 -C 5 ) -alkyl, (C 1 -C5) -alkylthio- (C 1 -C 5 ) -alkyl, (C 1 -C 5 ) -alkylsulfinyl- (C 1 -C 5 ) -alkyl, (C 1 -C 5 ) -alkylsulfonyl- (C 1 -C 5 ) -alkyl, (C 2 -C 8 ) -alkyleneaminoxy (C 1 -C 5 ) -alkyl, (C 1 -C 5 ) -alkylcarbonyl- (C 1 -C 5 ) -alkyl, (C 1 -C 5 ) -alkoxycarbonyl (C 1 -C 5 ) -alkyl, Aminocarbonyl- (C 1 -C 5 ) -alkyl, (C 1 -C 5 ) -alkylaminocarbonyl- (C 1 -C 5 ) -alkyl, (C 2 -C 8 ) -dialkylaminocarbonyl- (C 1 -C 5 ) -alkyl, (C 1 -C 5 ) -alkylcarbonylamino- (C 1 -C 5 ) -alkyl, N- (C 1 -C 5 ) -alkylcarbonyl-N- (C 1 -C 5 ) -alkylamino (C 1 -C 5 ) -alkyl, (C 3 -C 6 ) -trialkylsilyl- (C 1 -C 5 ) -alkyl, phenyl- (C 1 -C 5 ) -alkyl, wherein the phenyl groups can optionally also be substituted independently with 1,2 or 3 groups selected from (C 1 -C 3 ) -alkyl, (C 1 -C 3 ) -fluoroalkyl, (C 1 -C 2 ) -alkoxy, (C 1 -C 3 ) -fluoroalkoxy, (C 1 -C 3 ) -alkylthio, (C 1 -C 3 ) -alkylsulfinyl, (C 1 -C 3 ) -alkylsulfonyl, fluoro, chloro, bromo, cyano, nitro, or heteroaryl- (C 1 -C 5 ) -alkyl, wherein the heteroaryl group is optionally further independently substituted with 1, 2 or 3 are selected from (C 1 -C 3 ) -alkyl, (C 1 -C 3 ) -fluoroalkyl, (C 1 -C 2 ) -alkoxy, (C 1 -C 3 ) -fluoroalkoxy, (C 1 -C 3 ) -alkylthio, (C 1 -C 3 ) -alkylsulfinyl, (C 1 -C 3 ) -alkylsulfonyl, fluoro, chloro, bromo, cyano, nitro, or (C 2 -C 5 ) -fluoroalkenyl, (C 3 -C 8 ) -cycloalkyl, phenyl or phenyl substituted independently with 1, 2 or 3 groups selected from (C 1 -C 3 ) -alkyl, (C 1 -C 3 ) -fluoroalkyl, (C 1 -C 2 ) -alkoxy, (C 1 -C 3 ) -fluoroalkoxy, fluoro, chloro, bromo, cyano, nitro, or heteroaryl independently substituted with 1,2, or 3 groups selected from (C 1 -C 3 ) -alkyl, (C 1 -C 3 ) -fluoroalkyl, (C 1 -C 2 ) -alkoxy, (C 1 -C 3 ) -fluoroalkoxy, fluoro, chloro, bromo, cyano, nitro, R 15 is (C 1 -C 18 ) -alkyl, (C 3 -C 18 ) -alkenyl, (C 3 -C 18 ) -alkynyl, (C 2 -C 10 ) -fluoroalkyl, (C 1 -C 10 ) -cyanoalkyl, (C 1 -C 10 ) -nitroalkyl, (C 2 -C 10 ) -aminoalkyl, (C 1 -C 5 ) -alkylamino (C 1 -C 5 ) -alkyl, (C 2 -C 8 ) -dialkylamino (C 1 -C 5 ) -alkyl, (C 3 -C 7 ) -cycloalkyl- (C 1 -C 5 ) -alkyl, (C 1 -C 5 ) -alkoxy- (C 1 -C 5 ) -alkyl, (C 3 -C 5 ) -alkenyloxy- (C 1 -C 5 ) -alkyl, (C 3 -C 5 ) -alkynyloxy- (C 1 -C 5 ) -alkyl, (C 1 -C 5 ) -alkylthio- (C 1 -C 5 ) -alkyl, (C 1 -C 5 ) -alkylsulfinyl- (C 1 -C 5 ) -alkyl, (C 1 -C 5 ) -alkylsulfonyl- (C 1 -C 5 ) -alkyl, (C 2 -C 8 ) -Alkyleneaminoxy (C 1 -C 5 ) -alkyl, (C 1 -C 5 ) -alkylcarbonyl- (C 1 -C 5 ) -alkyl, (C 1 -C 5 ) -alkoxycarbonyl (C 1 -C 5 ) -alkyl, aminocarbonyl- (C 1 -C 5 ) -alkyl, (C 1 -C 5 ) -alkylaminocarbonyl- (C 1 -C 5 ) -alkyl, (C 2 -C 8 ) -dialkylaminocarbonyl- (C 1 -C 5 ) -alkyl, (C 1 -C 5 ) -alkylcarbonylamino- (C 1 -C 5 ) -alkyl, N- (C 1 -C 5 ) -alkylcarbonyl-N- (C 1 -C 5 ) -alkylamino (C 1 -C 5 ) -alkyl, (C 3 -C 6 ) -trialkylsilyl- (C 1 -C 5 ) -alkyl, Phenyl- (C 1 -C 5 ) -alkyl, wherein the phenyl group may also optionally be independently substituted with 1,2 or 3 groups selected from (C 1 -C 3 ) -alkyl, (C 1 -C 3 ) -fluoroalkyl, (C 1 -C 2 ) -alkoxy, (C 1 -C 3 ) -fluoroalkoxy, (C 1 -C 3 ) -alkylthio, (C 1 -C 3 ) -alkylsulfinyl, (C 1 -C 3 ) -alkylsulfonyl, Fluoro, chloro, bromo, cyano, nitro, or heteroaryl- (C 1 -C 5 ) -alkyl, wherein the heteroaryl group may also optionally be independently substituted with 1,2 or 3 groups selected from (C 1 -C 3 ) -alkyl, (C 1 -C 3 ) -fluoroalkyl, (C 1 -C 2 ) -alkoxy, (C 1 -C 3 ) -fluoroalkoxy, (C 1 -C 3 ) -alkylthio, (C 1 -C 3 ) -alkylsulfinyl, (C 1 -C 3 ) -alkylsulfonyl, fluoro, chloro, bromo, cyano, nitro, or (C 2 -C 5 ) -fluoroalkenyl, (C 3 -C 8 ) -cycloalkyl, phenyl or phenyl substituted independently with 1, 2 or 3 groups selected from (C 1 -C 3 ) -alkyl, (C 1 -C 3 ) -fluoroalkyl, (C 1 -C 2 ) -alkoxy, (C 1 -C 3 ) -fluoroalkoxy, fluoro, chloro, bromo, cyano, nitro, or heteroaryl substituted independently with 1,2, or 3 groups selected from (C 1 -C 3 ) -alkyl, (C 1 -C 3 ) -fluoroalkyl, (C 1 -C 2 ) -alkoxy, (C 1 -C 3 ) -fluoroalkoxy, fluorine, chlorine, bromine, cyano, nitro, R 16 and R 17 are independently hydrogen, (C 1 -C 10 ) -alkyl, (C 2 -C 10 ) -alkenyl, (C 2 -C 10 ) -alkynyl, (C 2 -C 10 ) -fluoroalkyl, (C 1 -C 10 ) -cyanoalkyl, (C 1 -C 10 ) -nitroalkyl, (C 1 -C 10 ) -aminoalkyl, (C 1 -C 5 ) -alkylamino (C 1 -C 5 ) -alkyl, (C 2 -C 8 ) -dialkylamino (C 1 -C 5 ) -alkyl, (C 3 -C 7 ) -cycloalkyl- (C 1 -C 5 ) -alkyl, (C 1 -C 5 ) -alkoxy- (C 1 -C 5 ) -alkyl, (C 3 -C 5 ) -alkenyloxy- (C 1 -C 5 ) -alkyl, (C 3 -C 5 ) -alkynyloxy- (C 1 -C 5 ) -alkyl, (C 1 -C 5 ) -alkylthio- (C 1 -C 5 ) -alkyl, (C 1 -C 5 ) -alkylsulfinyl- (C 1 -C 5 ) -alkyl, (C 1 -C 5 ) -alkylsulfonyl- (C 1 -C 5 ) -alkyl, (C 2 -C 8 ) -alkyleneaminoxy (C 1 -C 5 ) -alkyl, (C 1 -C 5 ) -alkylcarbonyl- (C 1 -C 5 ) -alkyl, (C 1 -C 5 ) -alkoxycarbonyl (C 1 -C 5 ) -alkyl, Aminocarbonyl- (C 1 -C 5 ) -alkyl, (C 1 -C 5 ) -alkylaminocarbonyl- (C 1 -C 5 ) -alkyl, (C 2 -C 8 ) -dialkylaminocarbonyl- (C 1 -C 5 ) -alkyl, (C 1 -C 5 ) -alkylcarbonylamino- (C 1 -C 5 ) -alkyl, N- (C 1 -C 5 ) -alkylcarbonyl-N- (C 1 -C 5 ) -alkylamino (C 1 -C 5 ) -alkyl, (C 3 -C 6 ) -trialkylsilyl- (C 1 -C 5 ) -alkyl, phenyl- (C 1 -C 5 ) -alkyl, wherein the phenyl groups can optionally also be substituted independently with 1,2 or 3 groups selected from (C 1 -C 3 ) -alkyl, (C 1 -C 3 ) -fluoroalkyl, (C 1 -C 2 ) -alkoxy, (C 1 -C 3 ) -fluoroalkoxy, (C 1 -C 3 ) -alkylthio, (C 1 -C 3 ) -alkylsulfinyl, (C 1 -C 3 ) -alkylsulfonyl, fluoro, chloro, bromo, cyano, nitro, heteroaryl- (C 1 -C 5 ) -alkyl, wherein the heteroaryl group is further optionally independently substituted with 1, 2 or 3 groups selected from (C 1 -C 3 ) -alkyl, (C 1 -C 3 ) -fluoroalkyl, (C 1 -C 2 ) -alkoxy, (C 1 -C 3 ) -fluoroalkoxy, (C 1 -C 3 ) -alkylthio, (C 1 -C 3 ) -alkylsulfinyl, (C 1 -C 3 ) -alkylsulfonyl, fluoro, chloro, bromo, cyano, nitro, or (C 2 -C 5 ) -fluoroalkenyl, (C 3 -C 8 ) -cycloalkyl, phenyl or independently 1, Phenyl substituted with 2 or 3 groups selected from (C 1 -C 3 ) -alkyl, (C 1 -C 3 ) -fluoroalkyl, (C 1 -C 2 ) -alkoxy, (C 1 -C 3 ) -fluoroalkoxy, Fluoro, chloro, bromo, cyano, nitro, or heteroaryl substituted independently with 1,2, or 3 groups selected from (C 1 -C 3 ) -alkyl, (C 1 -C 3 ) -fluoroalkyl, (C 1 -C 2 ) -alkoxy, (C 1 -C 3 ) -fluoroalkoxy, Fluoro, chloro, bromo, cyano, nitro, or heteroarylamino, wherein the heteroaryl group is independently substituted with 1, 2 or 3 groups selected from (C 1 -C 3 ) -alkyl, (C 1 -C 3 ) -fluoroalkyl, (C 1 -C 2 ) -alkoxy, (C 1 -C 3 ) -fluoroalkoxy, Fluoro, chloro, bromo, cyano, nitro, or di-heteroarylamino, wherein each heteroaryl group is independently substituted with 1, 2 or 3 groups selected from (C 1 -C 3 ) -alkyl, (C 1 -C 3 ) -fluoroalkyl, (C 1 -C 2 ) -alkoxy, (C 1 -C 3 ) -fluoroalkoxy, fluoro, chloro, bromo, cyano, nitro, or phenylamino, wherein the corresponding phenyl group is independently substituted with 1,2 or 3 groups selected from (C 1 -C 3 ) -alkyl, (C 1 -C 3 ) -fluoroalkyl, (C 1 -C 2 ) -alkoxy, (C 1 -C 3 ) -fluoroalkoxy, fluoro, chloro, bromo, cyano, nitro, or diphenylamino, wherein each phenyl group is independently substituted with 1,2 or 3 groups selected from (C 1 -C 3 ) -alkyl, (C 1 -C 3 ) -fluoroalkyl, (C 1 -C 2 ) -alkoxy, (C 1 -C 3 ) -fluoroalkoxy, fluoro, chloro, bromo, cyano, nitro, or (C 3 -C 7 ) -cycloalkylamino, Di- [ (C 3 -C 7 ) -cycloalkyl ] amino, (C 3 -C 7 ) -cycloalkoxy, or R 16 and R 17 , together with the nitrogen atom to which they are attached, form an unsubstituted 4 to 7 membered ring, which ring may optionally contain heteroatoms from O (oxygen) and S (sulfur), R 18 is (C 1 -C 10 ) -alkyl, (C 2 -C 10 ) -alkenyl, (C 2 -C 10 ) -alkynyl, (C 1 -C 10 ) -fluoroalkyl, (C 1 -C 10 ) -cyanoalkyl, (C 1 -C 10 ) -nitroalkyl, (C 1 -C 10 ) -aminoalkyl, (C 1 -C 5 ) -alkylamino (C 1 -C 5 ) -alkyl, (C 2 -C 8 ) -dialkylamino (C 1 -C 5 ) -alkyl, (C 3 -C 7 ) -cycloalkyl- (C 1 -C 5 ) -alkyl, (C 1 -C 5 ) -alkoxy- (C 1 -C 5 ) -alkyl, (C 3 -C 5 ) -alkenyloxy- (C 1 -C 5 ) -alkyl, (C 3 -C 5 ) -alkynyloxy- (C 1 -C 5 ) -alkyl, (C 1 -C 5 ) -alkylthio- (C 1 -C 5 ) -alkyl, (C 1 -C 5 ) -alkylsulfinyl- (C 1 -C 5 ) -alkyl, (C 1 -C 5 ) -alkylsulfonyl- (C 1 -C 5 ) -alkyl, (C 2 -C 8 ) -Alkyleneaminoxy (C 1 -C 5 ) -alkyl, (C 1 -C 5 ) -alkylcarbonyl- (C 1 -C 5 ) -alkyl, (C 1 -C 5 ) -alkoxycarbonyl (C 1 -C 5 ) -alkyl, aminocarbonyl- (C 1 -C 5 ) -alkyl, (C 1 -C 5 ) -alkylaminocarbonyl- (C 1 -C 5 ) -alkyl, (C 2 -C 8 ) -dialkylaminocarbonyl- (C 1 -C 5 ) -alkyl, (C 1 -C 5 ) -alkylcarbonylamino- (C 1 -C 5 ) -alkyl, N- (C 1 -C 5 ) -alkylcarbonyl-N- (C 1 -C 5 ) -alkylamino (C 1 -C 5 ) -alkyl, (C 3 -C 6 ) -trialkylsilyl- (C 1 -C 5 ) -alkyl, Phenyl- (C 1 -C 5 ) -alkyl, wherein the phenyl group is optionally further independently substituted with 1, 2 or 3 groups selected from (C 1 -C 3 ) -alkyl, (C 1 -C 3 ) -fluoroalkyl, (C 1 -C 2 ) -alkoxy, (C 1 -C 3 ) -fluoroalkoxy, (C 1 -C 3 ) -alkylthio, (C 1 -C 3 ) -alkylsulfinyl, (C 1 -C 3 ) -alkylsulfonyl, Fluoro, chloro, bromo, cyano, nitro, or heteroaryl- (C 1 -C 5 ) -alkyl, wherein the heteroaryl group is further optionally independently substituted with 1, 2 or 3 groups selected from (C 1 -C 3 ) -alkyl, (C 1 -C 3 ) -fluoroalkyl, (C 1 -C 2 ) -alkoxy, (C 1 -C 3 ) -fluoroalkoxy, (C 1 -C 3 ) -alkylthio, (C 1 -C 3 ) -alkylsulfinyl, (C 1 -C 3 ) -alkylsulfonyl, fluoro, chloro, bromo, cyano, nitro, or (C 2 -C 5 ) -fluoroalkenyl, (C 3 -C 8 ) -cycloalkyl, phenyl or phenyl independently substituted with 1,2 or 3 groups selected from (C 1 -C 3 ) -alkyl, (C 1 -C 3 ) -fluoroalkyl, (C 1 -C 2 ) -alkoxy, (C 1 -C 3 ) -fluoroalkoxy, fluoro, chloro, bromo, cyano, nitro, or heteroaryl independently substituted with 1, 2, or 3 groups selected from (C 1 -C 3 ) -alkyl, (C 1 -C 3 ) -fluoroalkyl, (C 1 -C 2 ) -alkoxy, (C 1 -C 3 ) -fluoroalkoxy, fluoro, chloro, bromo, cyano, nitro, or heteroarylamino, wherein the heteroaryl group is independently substituted with 1, 2, or 3 groups selected from (C 1 -C 3 ) -alkyl, (C 1 -C 3 ) -fluoroalkyl, (C 1 -C 2 ) -alkoxy, (C 1 -C 3 ) -fluoroalkoxy, fluoro, chloro, bromo, cyano, nitro, or di-heteroarylamino, wherein each heteroaryl group is independently substituted with 1, 2 or 3 are selected from (C 1 -C 3 ) -alkyl, (C 1 -C 3 ) -fluoroalkyl, (C 1 -C 2 ) -alkoxy, (C 1 -C 3 ) -fluoroalkoxy, Fluoro, chloro, bromo, cyano, nitro, or phenylamino, wherein the corresponding phenyl group is independently substituted by 1,2 or 3 groups selected from (C 1 -C 3 ) -alkyl, (C 1 -C 3 ) -fluoroalkyl, (C 1 -C 2 ) -alkoxy, (C 1 -C 3 ) -fluoroalkoxy, fluoro, chloro, bromo, cyano, nitro, or diphenylamino, wherein each phenyl group is independently substituted with 1,2 or 3 groups selected from (C 1 -C 3 ) -alkyl, (C 1 -C 3 ) -fluoroalkyl, (C 1 -C 2 ) -alkoxy, (C 1 -C 3 ) -fluoroalkoxy, fluoro, chloro, bromo, cyano, nitro, or (C 3 -C 7 ) -cycloalkylamino, di- [ (C 3 -C 7 ) -cycloalkyl ] amino, (C 3 -C 7 ) -cycloalkoxy, (C 1 -C 10 ) -alkoxy, (C 1 -C 10 ) -fluoroalkoxy, (C 3 -C 7 ) -alkylamino, Di- [ (C 3 -C 7 ) -alkyl ] amino; R 19 and R 20 are independently (C 1 -C 10 ) -alkyl, (C 2 -C 10 ) -alkenyl, (C 2 -C 10 ) -alkynyl, (C 1 -C 10 ) -fluoroalkyl, (C 1 -C 10 ) -cyanoalkyl, (C 1 -C 10 ) -nitroalkyl, (C 1 -C 10 ) -aminoalkyl, (C 1 -C 5 ) -alkylamino (C 1 -C 5 ) -alkyl, (C 2 -C 8 ) -dialkylamino (C 1 -C 5 ) -alkyl, (C 3 -C 7 ) -cycloalkyl- (C 1 -C 5 ) -alkyl, (C 1 -C 5 ) -alkoxy- (C 1 -C 5 ) -alkyl, (C 3 -C 5 ) -alkenyloxy- (C 1 -C 5 ) -alkyl, (C 3 -C 5 ) -alkynyloxy- (C 1 -C 5 ) -alkyl, (C 1 -C 5 ) -alkylthio- (C 1 -C 5 ) -alkyl, (C 1 -C 5 ) -alkylsulfinyl- (C 1 -C 5 ) -alkyl, (C 1 -C 5 ) -alkylsulfonyl- (C 1 -C 5 ) -alkyl, (C 2 -C 8 ) -alkyleneaminoxy (C 1 -C 5 ) -alkyl, (C 1 -C 5 ) -alkylcarbonyl- (C 1 -C 5 ) -alkyl, (C 1 -C 5 ) -alkoxycarbonyl (C 1 -C 5 ) -alkyl, Aminocarbonyl- (C 1 -C 5 ) -alkyl, (C 1 -C 5 ) -alkylaminocarbonyl- (C 1 -C 5 ) -alkyl, (C 2 -C 8 ) -dialkylaminocarbonyl- (C 1 -C 5 ) -alkyl, (C 1 -C 5 ) -alkylcarbonylamino- (C 1 -C 5 ) -alkyl, N- (C 1 -C 5 ) -alkylcarbonyl-N- (C 1 -C 5 ) -alkylamino (C 1 -C 5 ) -alkyl, (C 3 -C 6 ) -trialkylsilyl- (C 1 -C 5 ) -alkyl, phenyl- (C 1 -C 5 ) -alkyl, wherein the phenyl groups are optionally further independently substituted with 1, 2 or 3 groups selected from (C 1 -C 3 ) -alkyl, (C 1 -C 3 ) -fluoroalkyl, (C 1 -C 2 ) -alkoxy, (C 1 -C 3 ) -fluoroalkoxy, (C 1 -C 3 ) -alkylthio, (C 1 -C 3 ) -alkylsulfinyl, (C 1 -C 3 ) -alkylsulfonyl, fluoro, chloro, bromo, cyano, nitro, or heteroaryl- (C 1 -C 5 ) -alkyl, wherein the heteroaryl group is also optionally independently substituted with 1, 2 or 3 are selected from (C 1 -C 3 ) -alkyl, (C 1 -C 3 ) -fluoroalkyl, (C 1 -C 2 ) -alkoxy, (C 1 -C 3 ) -fluoroalkoxy, (C 1 -C 3 ) -alkylthio, (C 1 -C 3 ) -alkylsulfinyl, (C 1 -C 3 ) -alkylsulfonyl, fluoro, chloro, bromo, cyano, nitro, or (C 2 -C 5 ) -fluoroalkenyl, (C 3 -C 8 ) -cycloalkyl, phenyl or phenyl substituted independently with 1, 2 or 3 groups selected from (C 1 -C 3 ) -alkyl, (C 1 -C 3 ) -fluoroalkyl, (C 1 -C 2 ) -alkoxy, (C 1 -C 3 ) -fluoroalkoxy, fluoro, chloro, bromo, cyano, nitro, or heteroaryl independently substituted with 1,2, or 3 groups selected from (C 1 -C 3 ) -alkyl, (C 1 -C 3 ) -fluoroalkyl, (C 1 -C 2 ) -alkoxy, (C 1 -C 3 ) -fluoroalkoxy, fluoro, chloro, bromo, cyano, nitro, or heteroarylamino, wherein the heteroaryl group is independently substituted with 1, 2, or 3 groups selected from (C 1 -C 3 ) -alkyl, (C 1 -C 3 ) -fluoroalkyl, (C 1 -C 2 ) -alkoxy, (C 1 -C 3 ) -fluoroalkoxy, fluoro, chloro, bromo, cyano, nitro, or di-heteroarylamino, wherein each heteroaryl group is independently substituted with 1,2 or 3 groups selected from (C 1 -C 3 ) -alkyl, (C 1 -C 3 ) -fluoroalkyl, (C 1 -C 2 ) -alkoxy, (C 1 -C 3 ) -fluoroalkoxy, fluoro, chloro, bromo, cyano, nitro, or phenylamino, wherein the corresponding phenyl groups are independently substituted by 1, 2 or 3 are selected from (C 1 -C 3 ) -alkyl, (C 1 -C 3 ) -fluoroalkyl, (C 1 -C 2 ) -alkoxy, (C 1 -C 3 ) -fluoroalkoxy, Fluoro, chloro, bromo, cyano, nitro, or diphenylamino, wherein each phenyl group is independently substituted with 1, 2 or 3 groups selected from (C 1 -C 3 ) -alkyl, (C 1 -C 3 ) -fluoroalkyl, (C 1 -C 2 ) -alkoxy, (C 1 -C 3 ) -fluoroalkoxy, fluoro, chloro, bromo, cyano, nitro, or benzyloxy and phenyloxy, wherein the corresponding phenyl group is further optionally independently substituted with 1, 2 or 3 groups selected from (C 1 -C 3 ) -alkyl, (C 1 -C 3 ) -fluoroalkyl, (C 1 -C 2 ) -alkoxy, (C 1 -C 3 ) -fluoroalkoxy, fluoro, chloro, bromo, cyano, nitro group substitution, and R 21 is (C 1 -C 10 ) -alkyl, (C 3 -C 10 ) -alkenyl, (C 3 -C 10 ) -alkynyl, (C 1 -C 10 ) -fluoroalkyl, (C 1 -C 10 ) -cyanoalkyl, (C 1 -C 10 ) -nitroalkyl, (C 2 -C 10 ) -aminoalkyl, (C 1 -C 5 ) -alkylamino (C 1 -C 5 ) -alkyl, (C 2 -C 8 ) -dialkylamino (C 1 -C 5 ) -alkyl, (C 3 -C 7 ) -cycloalkyl- (C 1 -C 5 ) -alkyl, (C 1 -C 5 ) -alkoxy- (C 1 -C 5 ) -alkyl, (C 3 -C 5 ) -alkenyloxy- (C 1 -C 5 ) -alkyl, (C 3 -C 5 ) -alkynyloxy- (C 1 -C 5 ) -alkyl, (C 1 -C 5 ) -alkylthio- (C 1 -C 5 ) -alkyl, (C 1 -C 5 ) -alkylsulfinyl- (C 1 -C 5 ) -alkyl, (C 1 -C 5 ) -alkylsulfonyl- (C 1 -C 5 ) -alkyl, (C 2 -C 8 ) -Alkyleneaminoxy (C 1 -C 5 ) -alkyl, (C 1 -C 5 ) -alkylcarbonyl- (C 1 -C 5 ) -alkyl, (C 1 -C 5 ) -alkoxycarbonyl (C 1 -C 5 ) -alkyl, aminocarbonyl- (C 1 -C 5 ) -alkyl, (C 1 -C 5 ) -alkylaminocarbonyl- (C 1 -C 5 ) -alkyl, (C 2 -C 8 ) -dialkylaminocarbonyl- (C 1 -C 5 ) -alkyl, (C 1 -C 5 ) -alkylcarbonylamino- (C 1 -C 5 ) -alkyl, N- (C 1 -C 5 ) -alkylcarbonyl-N- (C 1 -C 5 ) -alkylamino (C 1 -C 5 ) -alkyl, (C 3 -C 6 ) -trialkylsilyl- (C 1 -C 5 ) -alkyl, Phenyl- (C 1 -C 5 -alkyl), wherein the phenyl group is optionally further independently substituted with 1, 2 or 3 groups selected from (C 1 -C 3 ) -alkyl, (C 1 -C 3 ) -fluoroalkyl, (C 1 -C 2 ) -alkoxy, (C 1 -C 3 ) -fluoroalkoxy, (C 1 -C 3 ) -alkylthio, (C 1 -C 3 ) -alkylsulfinyl, (C 1 -C 3 ) -alkylsulfonyl, Fluoro, chloro, bromo, cyano, nitro, or heteroaryl- (C 1 -C 5 ) -alkyl, wherein the heteroaryl group is further optionally independently substituted with 1, 2 or 3 groups selected from (C 1 -C 3 ) -alkyl, (C 1 -C 3 ) -fluoroalkyl, (C 1 -C 2 ) -alkoxy, (C 1 -C 3 ) -fluoroalkoxy, (C 1 -C 3 ) -alkylthio, (C 1 -C 3 ) -alkylsulfinyl, (C 1 -C 3 ) -alkylsulfonyl, fluoro, chloro, bromo, cyano, nitro, or phenoxy- (C 1 -C 5 ) -alkyl, wherein the phenyl groups are further optionally independently substituted with 1,2 or 3 groups selected from (C 1 -C 3 ) -alkyl, (C 1 -C 3 ) -fluoroalkyl, (C 1 -C 2 ) -alkoxy, (C 1 -C 3 ) -fluoroalkoxy, (C 1 -C 3 ) -alkylthio, (C 1 -C 3 ) -alkylsulfinyl, (C 1 -C 3 ) -alkylsulfonyl, fluoro, chloro, bromo, cyano, nitro, or heteroaryloxy- (C 1 -C 5 ) -alkyl, wherein the heteroaryl group is further optionally independently substituted with 1, 2 or 3 are selected from (C 1 -C 3 ) -alkyl, (C 1 -C 3 ) -fluoroalkyl, (C 1 -C 2 ) -alkoxy, (C 1 -C 3 ) -fluoroalkoxy, (C 1 -C 3 ) -alkylthio, (C 1 -C 3 ) -alkylsulfinyl, (C 1 -C 3 ) -alkylsulfonyl, fluoro, chloro, bromo, cyano, nitro, or phenyl independently substituted with 1, 2 or 3 groups selected from (C 1 -C 3 ) -alkyl, (C 1 -C 3 ) -fluoroalkyl, (C 1 -C 2 ) -alkoxy, (C 1 -C 3 ) -fluoroalkoxy, fluoro, chloro, bromo, cyano, nitro, or heteroaryl substituted independently with 1,2, or 3 groups selected from (C 1 -C 3 ) -alkyl, (C 1 -C 3 ) -fluoroalkyl, (C 1 -C 2 ) -alkoxy, (C 1 -C 3 ) -fluoroalkoxy, fluoro, chloro, bromo, cyano, nitro, or phenyl-C (=o), wherein the phenyl group is further optionally independently substituted with 1, 2, or 3 groups selected from (C 1 -C 3 ) -alkyl, (C 1 -C 3 ) -fluoroalkyl, (C 1 -C 2 ) -alkoxy, (C 1 -C 3 ) -fluoroalkoxy, fluorine, chlorine, bromine, cyano, nitro.
  2. 2. The herbicide/safener combination of claim 1 comprising as compound (a) a safener selected from one or more of compounds A1, A2, A3, A4, A5, A6, A7, A8, A9 and a10, wherein A1 Methyl = { [1, 5-bis (4-chloro-2-fluorophenyl) -1H-1,2, 4-triazol-3-yl ] oxy } acetate A2 = { [1, 5-bis (4-chloro-2-fluorophenyl) -1H-1,2, 4-triazol-3-yl ] oxy } acetic acid A3 Methyl = { [5- (4-chloro-2-fluorophenyl) -1- (2, 4-difluorophenyl) -1H-1,2, 4-triazol-3-yl ] oxy } acetate A4 = { [5- (4-chloro-2-fluorophenyl) -1- (2, 4-difluorophenyl) -1H-1,2, 4-triazol-3-yl ] oxy } acetic acid A5 Methyl = { [1- (4-chloro-2-fluorophenyl) -5- (2, 4-difluorophenyl) -1H-1,2, 4-triazol-3-yl ] oxy } acetate A6 = { [1- (4-chloro-2-fluorophenyl) -5- (2, 4-difluorophenyl) -1H-1,2, 4-triazol-3-yl ] oxy } acetic acid A7 Methyl = { [5- (4-bromo-2-fluorophenyl) -1- (2, 4-difluorophenyl) -1H-1,2, 4-triazol-3-yl ] oxy } acetate A8 = { [5- (4-bromo-2-fluorophenyl) -1- (2, 4-difluorophenyl) -1H-1,2, 4-triazol-3-yl ] oxy } acetic acid A9 Methoxy ethyl = { [1- (4-bromo-2-fluorophenyl) -5- (2, 4-difluorophenyl) -1H-1,2, 4-triazol-3-yl ] oxy } acetate A10 = { [1- (4-bromo-2-fluorophenyl) -5- (2, 4-difluorophenyl) -1H-1,2, 4-triazol-3-yl ] oxy } acetic acid 。
  3. 3. The herbicide/safener combination of claim 2 wherein (a) is selected from A1, A3, A5, A7 and A9.
  4. 4. A herbicide/safener combination as claimed in any one of claims 1 to 3 wherein (B) represents one or more compounds of formula (II) or an agrochemically acceptable salt thereof, wherein: Q is a group Q-1, R 1 is methyl, 1-propynyl or a six membered heteroaromatic ring containing one or two nitrogen atoms, wherein the heteroaromatic ring may be substituted by one R 9 group, R 2 is chlorine, methoxy, methyl or ethyl, R 3 is chlorine, methyl or ethyl, W is CH 2 , O, NH or N-CH 3 , Y is O or N-R 8 , Z is a connecting bond or CH 2 , N1 and n2 are independently 1 or 2, provided that n1+n2=2, 3 or 4, R 8 is (C 1 -C 4 ) -alkoxy, -C (O) (C 1 -C 4 ) -alkyl, -C (O) - (C 3 -C 6 ) -cycloalkyl, -C (O) O (C 1 -C 6 ) -alkyl, -S(O) 2 NHR1 7N ,-S(O)(=NH)R 19N ,-C(O)C(O)R 20N ,-C(O)C(R 23N )=N-O-R 24N ; R 9 is cyano or halogen; r 17N is methyl or ethyl; r 19N is methyl or ethyl; R 20N is methyl, ethyl or-NHR 22N ; R 22N N is methyl or ethyl; R 23N is methyl or ethyl; r 24N is methyl or ethyl; G is hydrogen, an agrochemically acceptable metal, C (O) -R 14 or-C (O) -O-R 15 , R 14 is (C 1 -C 6 ) -alkyl, R 15 is (C 1 -C 6 ) -alkyl.
  5. 5. The herbicide/safener combination of claim 4 wherein Q is Q-1 and R 1 、R 2 、R 3 , W, Y, Z and G and n1 and n2 are defined as follows: 。
  6. 6. a herbicide/safener combination as claimed in any one of claims 1 to 3 wherein (B) represents one or more compounds of formula (II) or an agrochemically acceptable salt thereof, wherein: Q is a group Q-2, R 1 is a 1-propynyl group, R 2 is chlorine, methoxy, methyl or ethyl, R 3 is chlorine, methyl or ethyl, W is CH 2 , O, NH or N-CH 3 , Y is N-R 8 , and the total number of the components is N-R 8 , Z is a connecting bond or CH 2 , N1 is a number of times which is 2, R 8 is (C 1 -C 4 ) -alkoxy, -C (O) (C 1 -C 4 ) -alkyl, -C (O) - (C 3 -C 6 ) -cycloalkyl or -S(O) 2 C(R 11N )R 12N R 13N ; R 11N is hydrogen; R 12N is hydrogen; R 13N is methyl; G is hydrogen, an agrochemically acceptable metal, C (O) -R 14 or-C (O) -O-R 15 , R 14 is (C 1 -C 6 ) -alkyl, R 15 is (C 1 -C 6 ) -alkyl.
  7. 7. The herbicide/safener combination of claim 6 wherein Q is Q-2 and Y and G have the following definitions, and wherein R 1 is 1-propynyl, R 2 and R 3 are each methyl, and W and Z are each CH 2 , and n1 is 2: 。
  8. 8. a herbicide/safener combination as claimed in any one of claims 1 to 3 wherein (B) represents one or more compounds of formula (II) or an agrochemically acceptable salt thereof, wherein: Q is a group Q-3, R 1 is a 1-propynyl group, R 2 is chlorine, methoxy, methyl or ethyl, R 3 is chlorine, methyl or ethyl, W is CH 2 , O, NH or N-CH 3 , Z is a connecting bond or CH 2 , R 1Q3 is hydrogen or (C 1 -C 6 ) -alkyl, R 2Q3 is- (CH 2 ) k -R 3Q3 ), Wherein R 3Q3 is selected from the group consisting of-C (O) NR 5N R 6N 、-NR 5N R 6N and-S (O) 2 NR 16N R 17N , And k is 0, and is preferably selected from the group consisting of, Or R 1Q3 and R 2Q3 together are- (CH 2 ) nq1 -C(R 4Q3 ) R 5Q3 -(CH 2 ) nq2 -where nq1 and nq2 are independently 1 or 2, R 4Q3 is hydrogen or (C 1 -C 6 ) -alkyl, R 5Q3 is selected from the group consisting of-C (O) NR 5N R 6N 、-NR 5N R 6N and-S (O) 2 NR 16N R 17N , Or R 4Q3 and R 5Q3 together are- (CH 2 )-N(R 8 )-(CH 2 ) -, R 8 is (C 1 -C 4 ) -alkoxy, -C (O) (C 1 -C 4 ) -alkyl, -C (O) - (C 3 -C 6 ) -cycloalkyl or -S(O) 2 C(R 11N )R 12N R 13N ; R 5N represents a substituent independently selected from hydrogen and (C 1 -C 6 ) -alkyl, R 6N represents a substituent independently selected from hydrogen, (C 1 -C 6 ) -alkyl and-C (O) -C (R 11N )R 12N R 13N ), R 11N is hydrogen; R 12N is hydrogen; r 13N is hydrogen or methyl; r 16N is hydrogen or (C 1 -C 6 ) -alkyl; R1 7N is hydrogen or (C 1 -C 6 ) -alkyl; G is hydrogen, an agrochemically acceptable metal, C (O) -R 14 or-C (O) -O-R 15 , R 14 is (C 1 -C 6 ) -alkyl, R 15 is (C 1 -C 6 ) -alkyl.
  9. 9. The herbicide/safener combination of claim 8 wherein Q is Q-3 and G has the following definition, and wherein R 1 is 1-propynyl, R 2 and R 3 are each methyl, W and Z are each CH 2 , and R 1Q3 is hydrogen, and R 2Q3 is-C (O) NR 5N R 6N , wherein R 5N and R 6N are each methyl: 。
  10. 10. The herbicide/safener combination of claim 8 wherein Q is Q-3 and R 5Q3 and G are defined as follows, and wherein R 1 is 1-propynyl, R 2 and R 3 are each methyl, and W and Z are each CH 2 , and wherein R 1Q3 and R 2Q3 groups together are- (CH 2 ) nq1 -C(R 4Q3 )R 5Q3 -(CH 2 ) nq2 -, wherein nq1 and nq2 are each 2, and R 4Q3 is hydrogen: 。
  11. 11. The herbicide/safener combination of claim 8 wherein Q is Q-3 and G has the following definition, and wherein R 1 is 1-propynyl, R 2 and R 3 are each methyl, and W and Z are each CH 2 , and wherein R 1Q3 and R 2Q3 groups together are- (CH 2 ) nq1 -C(R 4Q3 )R 5Q3 -(CH 2 ) nq2 -, wherein nq1 and nq2 are each 1, R 4Q3 and R 5Q3 groups together are- (CH 2 )-N(R 8 )-(CH 2 ) -, and wherein R 8 is- (CO) CH 3 : 。
  12. 12. The herbicide/safener combination of claim 5 wherein (a) is a3= { [5- (4-chloro-2-fluorophenyl) -1- (2, 4-difluorophenyl) -1H-1,2, 4-triazol-3-yl ] oxy } acetic acid methyl ester and (B) is selected from the group consisting of B1-6, B1-38, B1-42, B1-46, B1-66, and B1-68.
  13. 13. The herbicide/safener combination of any one of claims 1 to 12 further comprising one or more conventional additives in crop protection.
  14. 14. A method for protecting crop plants from the phytotoxic side effects of a herbicide (B), characterized in that an effective amount of a safener (A) is applied to the plants, plant parts, plant seeds or cultivation areas before, during or simultaneously with the application of the herbicide (B), wherein the combination of the herbicide (B) and safener (A) is as claimed in any of claims 1 to 12, Preferably, wherein the crop plant is a cereal plant, and/or The herbicide (B) is preferably applied at an application rate of 40 to 200 g/ha of active substance, and the safener (A)/herbicide (B) weight ratio is 1:400 to 500:1.
  15. 15. Use of the herbicide/safener combination of any one of claims 1 to 13 for controlling harmful plants or for regulating plant growth.

Description

Herbicide/safener combinations based on substituted [ (1, 5-diphenyl-1H-1, 2, 4-triazol-3-yl) oxy ] acetic acid safeners and substituted cyclodione herbicides and salts thereof The present invention relates to the field of crop protection compositions which can be used for inhibiting the growth of unwanted plants on cultivated land, for preparing seeds or for use in crop plants, comprising a combination of at least one safener (a) and at least one herbicide (B), wherein the safener (a) is one or more substituted [ (1, 5-diphenyl-1H-1, 2, 4-triazol-3-yl) oxy ] acetic acids of the general formula (I) and/or agrochemically acceptable salts thereof (=component (a)). The efficacy of known herbicides on harmful plants is at a high level, but generally depends on the application rate, the form of the corresponding formulation, the spectrum of harmful plants, the harmful plants to be controlled in each case, the climatic and soil conditions, etc., and also on the compatibility of the crop plants in particular. One approach to improving the application characteristics of herbicides may be to combine a safener with one or more active herbicidal ingredients that provide the desired additional characteristics. However, in the combined application of two or more active ingredients, it is not uncommon for the physical and biological incompatibility to occur, for example, lack of stability in the combined preparation, decomposition of the active ingredients and/or antagonism between the active ingredients, or limited scope of action of safeners, which only protect crop plants from injury by one herbicide, to be ineffective in the combined application of two or more herbicides. Safeners (also known as antidotes) having different chemical structures have been known for about 70 years. It is also known that they differ significantly in their protective function, which means that their use is limited to the herbicide chosen and/or the crop plants to be protected. Based on the harmful plants to be controlled, it is also desirable that the herbicide/safener combination selected does not adversely affect the herbicidal efficacy. [ (1, 5-Diphenyl-1H-1, 2, 4-triazol-3-yl) oxy ] acetic acid derivatives and salts thereof are known from PCT application No. PCT/EP2020/083167 (WO 2021/105101). Substituted cyclic diketones and salts thereof are known, for example, from PCT application No. WO 2021009229. It has now been found that substituted [ (1, 5-diphenyl-1H-1, 2, 4-triazol-3-yl) oxy ] acetic acid compounds are indeed effective for protecting different crop plants when one or more herbicides of the substituted cyclic diketone type (hereinafter referred to as "component (B)" ] are applied simultaneously. The herbicide/safener combinations of the invention interact in a particularly advantageous manner, for example, when they are used for controlling unwanted plant growth in crop plants, such as wheat (hard and soft wheat), maize, soybean, sugar beet, sugar cane, cotton, rice, beans (e.g. dwarf beans) and fava beans), flax, barley, oats, rye, triticale, potatoes and millet/sorghum. The present invention therefore provides a combination comprising as component (B) one or more active components (A) as safeners and one or more herbicidally active compounds, wherein (A) represents one or more compounds of the formula (I) or an agrochemically acceptable salt thereof, And wherein, (R a)p -phenyl represents a group Q-1.1 to Q-1.55: And (R b)q -phenyl represents a group of Q-2.1 to Q-2.55: R c is hydrogen, and the hydrogen atom, And R d is hydrogen, methyl, ethyl, n-propyl, isopropyl, n-butyl, n-pentyl, phenyl, benzyl, CH 2(4-Cl-Ph)、CH2(4-F-Ph)、CH2 (4-OMe-Ph), 2-methoxyethyl, tetrahydrofuran-2-yl-methyl, tetrahydrofuran-3-yl-methyl, tetrahydropyran-2-ylmethyl, tetrahydropyran-3-ylmethyl, tetrahydropyran-4-ylmethyl, methylpropan-3-yl, ethylpropionate-3-yl, methylacetate-2-yl, ethylacetate-2-yl, methylpentanoate-2-yl, ethylpivalate-3-yl, methyl-2-methylpropanoate-3-yl, methyl-2, 2-dimethylpropionate-3-yl, ethyl-2-methylpropanoate-3-yl, methyl-2-propionate-2-yl, ethyl-2-propionate-2-yl, ethylacetate-2-yl, methyl-1-methylcyclopropane-2-yl, ethylacetate-1-methylpropanoate-2-yl, ethylcyclopropane-2-yl, ethylformate-2-oxo-2, 3-fluoro-2, 3-fluoro-ethyl, 3-methylpropanoate-2-yl, fluoro-2-ethyl, 3-methylpropanoate, cyclopropylmethyl, 1-cyclopropyl-ethyl, (1-methylcyclopropyl) methyl, (2, 2-dichlorocyclopropyl) methyl, (2, 2-dimethylcyclopropyl) methyl, allyl, propargyl (prop-2-yn-1-yl), 2-chloroprop-2-en-1-yl, 3-phenylprop-2-yn-1-yl, 3-dichloroprop-2-en-1-yl, 3-dichloro-2-fluoroprop-2-en-1-yl, methylpropp-2-yn-1-yl, 2-methylpropp-2-en-1-yl but-2-en-1-yl, but-3-en-1-yl, but-2-yn-1-yl, but-3-yn-1-yl, 4-chlorobbut-2-yn-1-yl, 3-methylbutan-2-en-1-yl, 3-methylbutan-1-en-1-yl, 1- (2E) -1-methylbutan-2-en-1-yl, (E) -pent-3-en-2-yl or (Z) -pent-3-en-2-yl, cyclobutylmethyl, cyclopentylmethyl, cyclohexylmethyl, heptan-2-yl, isobutyl, 1, 3-dioxolan-2-ylmethyl or 1