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CN-122004231-A - Comprising an oxa carfentrazone-ethyl herbicide composition and application thereof

CN122004231ACN 122004231 ACN122004231 ACN 122004231ACN-122004231-A

Abstract

The invention discloses a weeding composition containing oxazomet and application thereof, and relates to the field of pesticides, wherein the effective components in the weeding composition comprise herbicide A and herbicide B, wherein the herbicide A is oxazomet, the herbicide B is an ALS inhibitor, the weight ratio of the herbicide A, B is 1-80:80-1, and the ALS inhibitor is one or more selected from penoxsulam, pyribenzoxim, bispyribac-sodium, pyriminobac-methyl, bensulfuron-methyl, pyrazosulfuron-ethyl, halosulfuron-methyl, fluazosulfuron-methyl, flupyrazosulfuron-ethyl and propyrisulfuron-ethyl. The composition provided by the invention is compounded by the oxazasultone and two medicaments with different mechanisms, so that the composition has an obvious gain effect on preventing and killing weeds such as barnyard grass in paddy fields, and the use amount of active ingredients can be reduced.

Inventors

  • MENG LINGTAO
  • CAO HONGYU
  • YIN YULIANG
  • CUI SHASHA
  • LIU YI

Assignees

  • 山东滨农科技有限公司

Dates

Publication Date
20260512
Application Date
20241111

Claims (10)

  1. 1. The herbicide composition containing the oxazophos is characterized in that active ingredients of the herbicide composition comprise herbicide A and herbicide B, wherein the herbicide A is the oxazophos, the herbicide B is an ALS inhibitor, and the weight ratio of the herbicide A, B is 1-80:80-1; The chemical structural formula of the oxazophos is as follows:
  2. 2. The herbicide composition of claim 1, wherein the weight ratio of herbicide A, B is 1-60:60-1, optionally 1-50:50-1, optionally 1-40:40-1, optionally 1-30:30-1, optionally 1:20-20:1, optionally 1:15-15:1, optionally (15:1) - (5:6), optionally (15:2) - (5:5), optionally (15:1) - (5:5), optionally (10:1) - (5:5), optionally (5:1) - (5:5), optionally (15:1) - (5:1), optionally (15:1) - (5:1) (5:1), Optionally (10:1) to (10:3), optionally 15:1, 10:1, 15:2, 5:1, 10:3, 3:1, 5:2, 5:3, 5:4, 5:5, 5:6.
  3. 3. The herbicide composition according to claim 1 or 2, wherein the ALS inhibitor is selected from one or more of penoxsulam, pyribenzoxim, bispyribac-sodium, pyriminobac-methyl, bensulfuron-methyl, pyrazosulfuron-ethyl, halosulfuron-methyl, flucarbazone-methyl, flupyrazosulfuron-ethyl, propyrisulfuron-methyl; when the herbicide B comprises penoxsulam, the weight ratio of oxazophos to penoxsulam is (5:1) to (1:1) (1:1), Optionally in a weight ratio of 5:1, 3:1, 5:3 or 1:1; or when the herbicide B comprises the florasulam, the weight ratio of the oxazophos to the florasulam is (5:1) - (1:1), and optionally the weight ratio is 5:1, 3:1, 5:3 or 1:1; or when the herbicide B comprises pyrazosulfuron, the weight ratio of the oxazamate to the pyrazosulfuron is (15:1) - (5:1), and the weight ratio is optionally 15:1 or 5:1; or when the herbicide B comprises bensulfuron-methyl, the weight ratio of oxazamate to bensulfuron-methyl is (15:2) - (5:6), and optionally the weight ratio is 15:2, 5:2, 5:4 or 5:6; or when the herbicide B comprises bispyribac-sodium, the weight ratio of the oxazophos to the bispyribac-sodium is (15:1) - (5:5), and optionally the weight ratio is 15:1, 5:1, 3:1, 5:3 or 1:1; Or when the herbicide B comprises pyribenzoxim, the weight ratio of the oxazophos to the pyribenzoxim is (10:1) - (10:3), and optionally the weight ratio is 10:1, 10:2 or 10:3; or when the herbicide B comprises halosulfuron-methyl, the weight ratio of oxazosulfuron to halosulfuron-methyl is (15:2) - (5:2), and optionally the weight ratio is 5:2, 5:1 or 15:2.
  4. 4. The herbicide composition of claim 3, wherein when the herbicide B is penoxsulam or triafamone, the weight ratio of herbicide A, B is (5-15): (1-5), optionally the weight ratio is 5:1, 3:1, 5:3 or 1:1; or when the herbicide B is pyrazosulfuron, the weight ratio of the herbicide A, B is (15:1) - (5:1), and optionally the weight ratio is 15:1 or 5:1; or when the herbicide B is bensulfuron-methyl or bispyribac-sodium, the weight ratio of the herbicide A, B is (15:1) - (5:6), optionally (15:2) - (5:5), optionally the weight ratio is 15:1, 15:2, 5:1, 3:1, 5:3, 5:2, 5:4, 5:5 or 5:6; or when the herbicide B is pyribenzoxim, the weight ratio of the herbicide A, B is (10:1) - (10:3), optionally the weight ratio is 10:1, 10:2 or 10:3; Or when the herbicide B is halosulfuron-methyl, the weight ratio of the herbicide A, B is (15:2) - (5:2), optionally the weight ratio is 5:2, 5:1 or 15:2.
  5. 5. A herbicidal composition according to any of claims 1 to 4, wherein the active ingredient comprises 1-95wt%, optionally 5% -80wt%, optionally 6% -45wt% of the total weight of the composition.
  6. 6. The herbicide composition according to any one of claims 1 to 5, wherein the herbicide composition is in the form of a dispersible oil suspension, an aqueous suspension, a suspoemulsion, a wettable powder, an emulsifiable concentrate, a water dispersible granule, an aqueous emulsion or a microemulsion; and/or the weeding composition further comprises an auxiliary agent, wherein the auxiliary agent is selected from one or more of a safener, a dispersing agent, a wetting agent, an emulsifying agent, a solvent, a cosolvent, an antifreezing agent, a stabilizer, a preservative, a thickening agent, a binding agent, a defoaming agent, an acid-regulating medium, an alkali-regulating medium and a solid inert carrier.
  7. 7. The herbicide composition of claim 6, wherein the safener is selected from one or more of bisbenzoxazole acid, cyprosulfamide, pyraclonil, cloquintocet-mexyl, gibberellic acid, furilazole, and METCAMIFEN; and/or the dispersing agent comprises one or more of sodium lignin sulfonate, calcium lignin sulfonate, sodium polyacrylate, methylene dinaphthyl sulfonate, calcium alkylbenzenesulfonate, alkylbenzene sulfonate amine salt, methylene dinaphthyl sulfonate sodium formaldehyde condensate, polyoxyethylene polyoxypropylene segmented copolymer, carboxymethyl cellulose, polyvinyl alcohol, polyvinylpyrrolidone, polycarboxylate, alkyl naphthalene sulfonate polycondensate and the like; And/or the wetting agent comprises one or more of nekal, sodium dodecyl sulfate, condensate of fatty alcohol and ethylene oxide, fast T, naphthalene sulfonic acid formaldehyde condensate, alkyl naphthalene sulfonate, aryl polyoxyethylene ether phosphate, alkyl sulfate, sodium alkylaryl sulfonate, alkylphenol polyoxyethylene ether phosphate, fatty alcohol polyoxyethylene ether, sorbitan fatty acid ester polyoxyethylene ether, azone and organic silicon wetting agent; And/or the emulsifier comprises one or more of pesticide emulsion 400#, pesticide emulsion 500#, pesticide emulsion 600#, pesticide emulsion 700#, NP series, 0201B, 0203B, 2201, ningru 31 # and Ningru 33 # and Ningru 37 # and 0202C, block polyether, alkylphenol polyoxyethylene ether sulfosuccinate, castor oil polyoxyethylene ether, fatty acid polyoxyethylene ether, polyoxyethylene fatty alcohol ether, ethoxylated castor oil, polymethyl acrylate, fatty acid polyethylene glycol ester, glycerol trilaurate polyoxyethylene ether and the like; And/or the solvent comprises one or more of acetone, butanone, cyclohexanone, toluene, xylene, trimethylbenzene, tetramethylbenzene, methylnaphthalene, methyl oleate, ethyl acetate, fatty acid methyl ester, pine-based oil, soybean oil, rapeseed oil, biodiesel, ethanol, N-propanol, isopropanol, propylene glycol, glycerol, N-butanol, isooctanol, sec-butyl acetate, dimethyl carbonate, diesel oil, white oil, engine oil, dibasic ester, N-methylpyrrolidone, N-dimethylformamide, isophorone, deionized water and the like; And/or the cosolvent comprises one or more of ethanol, n-propanol, isopropanol, propylene glycol, glycerol, n-butanol, isooctanol and the like; and/or the antifreezing agent comprises one or more of sorbitol, ethylene glycol, polyethylene glycol, propylene glycol, glycerol, urea and sodium chloride; And/or the stabilizer comprises one or more of sodium citrate, resorcinol, epoxidized soybean oil, epichlorohydrin, epoxidized linseed oil, pentaerythritol, xylitol, butyl hydroxy anisole and the like; and/or the preservative comprises one or more of formaldehyde, benzoic acid, sodium benzoate, potassium sorbate, kathon, isothiazolinone and the like; And/or the thickener comprises one or more of xanthan gum, gelatin, acacia, polyvinyl alcohol, bentonite, magnesium aluminum silicate, carboxymethyl cellulose, carboxyethyl cellulose, methyl cellulose and the like; And/or the binder comprises one or more of glucose, sucrose, hydroxyethyl cellulose, soluble starch, polyethylene glycol, methyl cellulose, polycarboxylic acid and water-soluble high molecular compound sodium carboxymethyl cellulose, polyvinyl alcohol, paraffin, gypsum, hydroxypropyl methyl cellulose, polyacrylamide and the like; And/or the defoamer comprises one or more of C8-10 fatty alcohol compounds, epoxidized soybean oil, ethanol, silicone compounds, organic silicone oil and C10-20 saturated fatty acid compounds; and/or the acid regulating medium comprises one or more of organic acids such as benzoic acid, citric acid, acetic anhydride, propionic acid, methanesulfonic acid and the like, and inorganic acids such as hydrochloric acid, sulfuric acid, phosphoric acid and the like; And/or the alkali regulating medium comprises one or more of organic alkali such as ethylenediamine, triethylamine, triethanolamine, triisopropanolamine, ammonia water, urea and the like, inorganic alkali or salt such as sodium carbonate, sodium bicarbonate, sodium hydroxide and the like; And/or the solid inert carrier comprises one or more of light calcium carbonate, diatomite, bentonite, attapulgite, white carbon black, kaolin and corn starch.
  8. 8. The herbicide composition according to any one of claims 1 to 7, which is used for controlling one or more of barnyard grass, snakehead intestines, moleplant seed, nutgrass flatsedge, peanut, heteromorphic nutgrass, crab grass, glossoside, amaranthus spinosus, polygonum caryophyllum, buddleia and solar floating grass, and optionally for controlling harmful weeds in paddy fields.
  9. 9. Use of a herbicide composition according to any one of claims 1 to 8 for combating harmful weeds in crop fields.
  10. 10. The use according to claim 9, wherein the harmful weeds are one or more of barnyard grass, snakehead intestine, moleplant seed, nutgrass flatsedge, peanut, heteromorphic nutgrass, crab grass, glossoside, amaranthus tricolor, polygonum syringae, comfrey, solar floating grass, optionally for controlling harmful weeds in paddy fields.

Description

Comprising an oxa carfentrazone-ethyl herbicide composition and application thereof Technical Field The invention relates to the technical field of pesticides, in particular to a herbicide composition containing oxazophos and application thereof. Background The information provided in this background section is only for enhancement of understanding of the general background of the invention and should not be taken as an acknowledgement or any form of suggestion that this information forms the prior art already known to a person of ordinary skill in the art. Chemical weeding is the most economical and effective means in farmland weed control, but as a plurality of weeds are mixed in a paddy field generally, the resistance of the weeds in the paddy field is increased, the control difficulty is increased, and the weeds in the paddy field cannot be controlled once by a single effective component. Reasonable compounding or compounding of herbicide compounds can have the advantages of improving the efficacy, delaying the resistance, expanding the weed killing spectrum and the like, and is an important means for solving the weed problem. Therefore, there is an urgent need for a good herbicide composition effective in controlling weeds in paddy fields in agricultural production. The active ingredient oxazophos is HPPD high-selectivity systemic conduction type paddy field herbicide innovatively developed by Shandong Kogyo technology Co-Ltd, has high safety to paddy rice, mainly causes new She Baihua weeds through absorption of plant roots and stems, and has good effects on annual weeds such as barnyard grass, moleplant, special-shaped nutgrass flatsedge, snakehead intestines and the like. The oxazophos is mixed with agents with different action mechanisms, so that the oxazophos can be used in paddy fields at one time, all annual weeds can be prevented and removed, the labor cost of vast growers is reduced, and the problem of paddy field weeds is solved by the simplest method. Disclosure of Invention Object of the Invention In order to overcome the defects, the invention aims to provide the herbicide composition containing the oxazomet and the application thereof, and the composition can effectively prevent and remove the weeds such as barnyard grass, moleplant, crabgrass, glossodes canadensis, snakehead intestines, amaranthus tricolor, polygonum syringae, lovely sprouts, special-shaped nutgrass galingale, sun floating grass and the like in a crop field, and has the characteristics of expanding a weed killing spectrum, improving the preventing and removing effect, eliminating the harm of weeds, preventing and removing the resistance, reducing the dosage, saving the cost, reducing the environmental pressure and the like. Solution scheme In order to achieve the purpose of the invention, the technical scheme adopted by the invention is as follows: In a first aspect, the invention provides a herbicide composition containing oxazophos, which comprises an active ingredient of herbicide A and herbicide B, wherein the herbicide A is oxazophos, the herbicide B is an ALS inhibitor, and the weight ratio of the herbicide A, B is 1-80:80-1; The chemical structural formula of the oxazophos is as follows: Further, the weight ratio of the herbicide A, B is 1-60:60-1, optionally 1-50:50-1, optionally 1-40:40-1, optionally 1-30:30-1, optionally 1:20-20:1, optionally 1:15-15:1, optionally (15:1) - (5:6), Optionally (15:2) - (5:5), optionally (15:1) - (5:5), optionally (10:1) - (5:5), optionally (5:1) - (5:5), optionally (15:1) - (5:1), optionally (10:1) - (10:3), Alternatively 15:1, 10:1, 15:2, 5:1, 10:3, 3:1, 5:2, 5:3, 5:4, 5:5, 5:6. Further, the ALS inhibitor is selected from one or more of penoxsulam, pyribenzoxim, bispyribac-sodium, pyriminobac-methyl, bensulfuron-methyl, pyrazosulfuron-ethyl, halosulfuron-methyl, flucarbazone-sodium, flupyrsulfuron-ethyl and propyrisulfuron-methyl, when the herbicide B comprises penoxsulam, the weight ratio of oxazasulfuron to penoxsulam is (5:1) to (1:1), and optionally the weight ratio is 5:1, 3:1, 5:3 or 1:1; when the herbicide B comprises the florasulam, the weight ratio of the oxazophos to the florasulam is (5:1) to (1:1), Optionally in a weight ratio of 5:1, 3:1, 5:3 or 1:1; When the herbicide B comprises pyrazosulfuron, the weight ratio of the oxazosulfuron to the pyrazosulfuron is (15:1) - (5:1), Optionally in a weight ratio of 15:1 or 5:1; When the herbicide B comprises bensulfuron-methyl, the weight ratio of oxazosulfuron to bensulfuron-methyl is (15:2) - (5:6), Optionally in a weight ratio of 15:2, 5:2, 5:4 or 5:6; When the herbicide B comprises bispyribac-sodium, the weight ratio of the oxazophos to the bispyribac-sodium is (15:1) - (5:5), and optionally the weight ratio is 15:1, 5:1, 3:1, 5:3 or 1:1; When the herbicide B comprises pyribenzoxim, the weight ratio of the oxazophos to the pyribenzoxim is (10:1) - (10: 3) Optionally in a weight ratio of 10:1, 10:2 or 10:3; when the herbici