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EP-4414436-B1 - THERMAL FLUID USED INSIDE ALUMINIUM THERMAL EMITTERS, REPLACING MINERAL OIL DERIVED FROM PETROLEUM

EP4414436B1EP 4414436 B1EP4414436 B1EP 4414436B1EP-4414436-B1

Inventors

  • PINEDA ALVAREZ, Jose Manuel

Dates

Publication Date
20260506
Application Date
20211006

Claims (2)

  1. Thermal fluid used inside aluminium thermal emitters, replacing mineral oil derived from petroleum, characterised by using water (H2O) as a heat dissipation fluid to which the following substances are added in the approximate proportions by weight indicated: - Between 0.4% and 4% carboxymethyl cellulose. - Between 0.5% and 3% potassium silicate. - Between 0.5% and 0.4% sodium carbonate.
  2. Thermal fluid used inside aluminium thermal emitters, replacing mineral oil derived from petroleum, according to claim 1, characterised in that the chemical substance with alkaline properties is sodium carbonate.

Description

Thermal fluid used inside aluminium thermal emitters, replacing mineral oil derived from petroleum. OBJECT OF THE INVENTION The invention, as expressed in the statement of this descriptive report, refers to a biodegradable and ecological fluid, which is used inside aluminium thermal emitters, replacing mineral oil derived from petroleum. The field of application of the present invention is the chemical sector and, more specifically, the air conditioning industry, and its application is in aluminium-based thermal emitters used in heating systems in general. BACKGROUND OF THE INVENTION The "heat dissipation fluid," like any liquid, is stored in a device for this purpose. When heated using electrical resistance, it circulates inside the circuits of the device because of the difference in pressures that are generated, thereby heating its surrounding environment. Oil-based fluids are usually used in industrial heating systems with thermal oil, using a combustion chamber through a coil. Thus, in these applications, the coil takes energy from combustion, through the low-pressure pumped oil system that circulates through it. This leads it to behave like a thermal fluid that, by heating the coils, transmits the heat indirectly to a consumer, making use of the pertinent hydraulic circuit. Another common application of oil is as a thermal fluid inside a radiator, with a function very similar to the industrial use of thermal oil. In these applications, the radiator connected to the electrical network provides energy in the form of heat through resistors placed inside it. Specifically, these resistors are in direct contact with the fluid or thermal oil contained therein. This provides them with the necessary heat and pressure for it to expand, and to cause the corresponding flow of oil through the interior of the pipe circuit that contains the radiator, until it heats the environment that surrounds it. Oil comes from petroleum and, therefore, fossil fuels. The drawback of this is that it is frequently discharged into the environment without any control, making it a highly polluting fluid. Thus, the technical problem to be solved is the need to change the oil as a heat dissipation fluid (such as highly refined mineral oil for its production as a petroleum derivative and, therefore, from fossil fuels), for another fluid that does not come from fossil fuels. This would improve the environmental impact of the devices that use it both throughout their useful life and afterwards, once it has become waste. The invention of the same applicant with publication number WO2021/105531, called "Heat transfer fluid with a composition based on the use of water," is known as the closest in the state of the art. It consists of the substitution of the thermal oil as a heat dissipation fluid, with another water-based fluid to which a set of constituents are added that gives it the appropriate characteristics to be used as a thermal fluid. This prevents it from producing the usual corrosion on the containers upon contact with water and also provides the following advantages: ✔ Savings in electrical consumption of around 30%, when comparing the use of a conventional thermal oil radiator to that which the fluid of the invention would use, maintaining the same thermal performance.✔ It allows the thermal oils present on the market to be directly replaced, since incorporating carboxymethyl cellulose increases the viscosity of the resulting fluid. This makes it similar to that of a conventional thermal oil used as a heat sink in most heat generating devices.✔ Reduction of the environmental impact associated with the use of the fluid proposed to replace thermal oil, as it does not include any fossil fuel-derived substance.✔ Water acquisition cost. However, after numerous trials and technical tests, it has been found that the thermal fluid of the aforementioned invention contains a formulation that does not meet its goal when the radiators are made from aluminium. Thus, compared to the previous patent, this invention provides the improvement consisting of the use of sodium carbonate instead of sodium hydroxide. This is because it has been found that due to the production of hydrogen gas, when aluminium is brought into contact with sodium hydroxide, a pressure is created inside its container, so it is not possible to use sodium hydroxide with aluminium. For this reason, it was necessary to adjust and change the fluid formulation. Although one constituent has been substituted for another in its composition, this substitution makes the resulting Fluid appropriate for the intended aluminium emitter-related purpose. The previous composition, in the terms already mentioned, made its application impossible in the said emitters, given that containing sodium hydroxide generated pressure inside the container, making it technically impossible to use sodium hydroxide with aluminium, as described in the previous invention. As previously mentioned, this substitu