JP-2022514616-A5 -

Dates

Publication Date

20221226

Application Date

20191223

Description

Although the present invention has been described by some of the above embodiments, the present invention should not be construed as being limited thereto, but rather as encompassing the general scope disclosed above. Various modifications and embodiments can be made without departing from the spirit and scope of the present invention. The matters disclosed in this specification include the following: [1] Compositions containing the following: a) One or more monomers of formula (I): During the ceremony, m is an integer of 0, 1, or 2; It is either a single bond or a double bond; R1 , R2 , R3 , and R4 are the same or different, and each independently contains hydrogen, halogen, methyl, ethyl, linear or branched (C3 - C16 ) alkyl, (C2 - C16 ) alkenyl, perfluoro(C1 - C12 ) alkyl, (C3 - C12 ) cycloalkyl, (C6 - C12 ) bicycloalkyl, (C7 - C14 ) tricycloalkyl, methoxy, ethoxy, linear or branched (C3 - C16 ) alkoxy, (C2 - C6 ) acyl, (C2 - C6 ) acyloxy, (C6 - C14 ) aryl, (C6 - C14 ) aryl( C1 - C6 ) alkyl, perfluoro(C6 - C14 ) Selected from the group consisting of aryl, perfluoro(C6 - C14 ) aryl(C1 - C3 ) alkyl, (C6 - C14 ) aryloxy, (C6 - C14 ) aryl( C1 - C6 )alkoxy, tri(C1 - C6 ) alkoxysilyl and the group of formula (A): -Z-Aryl (A) During the ceremony, Z is a bond or a group selected from the following: (CR 5 R 6 ) a , O(CR 5 R 6 ) a , (CR 5 R 6 ) a O, (CR 5 R 6 ) a - O - (CR 5 R 6 ) b , (CR 5 R 6 ) a - O - (SiR 5 R 6 ) b , (CR 5 R 6 ) a - (CO) O - ( CR 5 R 6) b, ( CR 5 R 6 ) a - O ( CO ) - (CR 5 R 6 ) b , ( CR 5 R 6 ) a - (CO) - (CR 5 R 6 ) b , where a and b are integers that may be the same or different, and each is independently between 1 and 12; R5 and R6 are the same or different, and each is independently selected from the group consisting of hydrogen, methyl, ethyl, linear or branched (C3 - C6 ) alkyl , methoxy, ethoxy, linear or branched (C3 - C6 ) alkyloxy, (C2 - C6 ) acyl, (C2 - C6 ) acyloxy, phenyl, and phenoxy; Aryl is phenyl, or phenyl substituted with one or more groups selected from groups consisting of methyl, ethyl, linear or branched (C3 - C6 ) alkyl, hydroxy, methoxy, ethoxy, linear or branched (C3 - C6 ) alkyloxy, ( C2 - C6 ) acyl, (C2 - C6 ) acyloxy, phenyl, and phenoxy; or One of R1 or R2 , together with one of R3 or R4 and the carbon atom to which they are bonded, forms a (C5-C7) carbocyclic ring optionally containing one or more double bonds; b) Optionally, one or more monomers of formula (IV): During the ceremony, R16 and R17 are the same or different, and each is independently selected from the group consisting of hydrogen, methyl, ethyl, linear or branched (C3 - C6 ) alkyl , methoxy, ethoxy, linear or branched (C3 - C6 ) alkyloxy, acetoxy, (C2 - C6 ) acyl, phenyl, and phenoxy; or R 16 , together with R 17 and the carbon atoms to which they are bonded, forms a (C 5 - C 7 ) carbon ring optionally containing one or more double bonds; R 18 is hydrogen, halogen, methyl, ethyl, linear or branched (C3 - C16 ) alkyl, (C6 - C10 ) aryl, (C6 - C10 ) aryl(C1 - C6 ) alkyl, hydroxy, methoxy, ethoxy, linear or branched (C3 - C16 ) alkoxy, (C6 - C10 ) aryloxy, ( C6 - C10 )aryl(C1 - C6 ) alkoxy, -O(CO)R 19 and -O(CO)OR 19 , where R 19 is methyl, ethyl, linear or branched (C3 - C16 ) alkyl, (C6 - C10 ) aryl and (C6 - C10 ) aryl(C1 - C6 ) alkyl; c) One or more compounds selected from the group consisting of the following: Here, m is an integer of 0, 1, or 2; b is an integer between 1 and 10; K is selected from the group consisting of CH₂, CH₂-CH₂, O , and S ; X is selected from the group consisting of O, S, NR a , SiR b R c , SiR b R c O (SiR b R c O) n SiR b R c , SiR b R c (C 6 - C 10 ) arylSiR b R c , -C(O)-, -C(O)O-, -OC(O)-, -OC(O)-O-, -S-C(O)-, -C(O)-S-, -CH=CH-, and -CC-; Ra , Rb , and Rc are independently selected from the group consisting of hydrogen, methyl, ethyl, or linear or branched (C3 - C12 ) alkyl , (C3 - C8 ) cycloalkyl, ( C6 - C12 ) bicycloalkyl, (C6 - C12 ) bicycloalkenyl, and ( C6 - C12 ) bicycloalkenyl ( C1 - C3 ) alkylSi(CH3 ) 2 , and the O, NRa and /or S atoms are not directly bonded to each other; and n is an integer between 0 and 10; d) Potential organic transition metal catalysts comprising a metal selected from the group consisting of ruthenium and osmium; and e) Compounds that can release Brønsted acid under photodegradation conditions; where The aforementioned composition is in the form of a transparent liquid at room temperature. [2] The composition according to [1] above, wherein the composition comprises first and second monomers of formula (I) which are different from each other, one of the first and second monomers having a viscosity of less than 50 centipoise, and the first monomer is completely miscible with the second monomer to form a clear solution. [3] The composition according to [1] above, wherein the composition comprises a monomer of formula (I) in which m is 1 and each of R1 , R2 , R3 , and R4 is hydrogen. [4] The composition according to [3] above, wherein th