US-12620532-B2 - Multilayer ceramic capacitor and manufacturing method thereof

Abstract

A multilayer ceramic capacitor and a method of manufacturing the same. The multilayer ceramic capacitor includes a capacitor body including a dielectric layer and an internal electrode layer; and an external electrode disposed outside the capacitor body. The external electrode includes a lower layer positioned on a cross-section of the capacitor body to be electrically connected to the internal electrode layer, and an upper layer to cover the lower layer and positioned on the lower layer. The lower layer includes a first glass including aluminum (Al) in an amount of more than 0 atom % to 8 atom % or less with respect to a total amount of components of the first glass. The upper layer includes a second glass including aluminum (Al) in an amount of 10 atom % or more to 20 atom % or less with respect to a total amount of components of the second glass.

Inventors

• Jaehoon Bang
• Youngah Song
• Bonggyu Choi
• Kwang Dong SEONG
• Dokyeong Lee
• Wansik Kim

Assignees

• SAMSUNG ELECTRO-MECHANICS CO., LTD.

Dates

Publication Date

20260505

Application Date

20240116

Priority Date

20231027

Claims (20)

1. 1 . A multilayer ceramic capacitor, comprising: a capacitor body comprising a dielectric layer and an internal electrode layer; and an external electrode disposed outside the capacitor body; wherein the external electrode comprises a lower layer positioned on a cross-section of the capacitor body to be electrically connected to the internal electrode layer, and an upper layer to cover the lower layer and positioned on the lower layer, wherein the lower layer comprises a first glass that comprises aluminum (Al) in an amount of more than 0 atom % to 8 atom % or less with respect to a total amount of components of the first glass, and wherein the upper layer comprises a second glass that comprises aluminum (Al) in an amount of 10 atom % or more to 20 atom % or less with respect to a total amount of components of the second glass.
2. 2 . The multilayer ceramic capacitor of claim 1 , wherein a ratio of the amount of aluminum (Al) comprised in the second glass to the amount of aluminum (Al) comprised in the first glass is more than 2 to 100.
3. 3 . The multilayer ceramic capacitor of claim 1 , wherein the second glass further comprises lithium (Li), sodium (Na), iron (Fe), barium (Ba), calcium (Ca), zinc (Zn), boron (B), silicon (Si), tin (Sn) or a combination thereof.
4. 4 . The multilayer ceramic capacitor of claim 3 , wherein: the second glass comprises silicon (Si); and a sum of components of aluminum (Al) and silicon (Si) is 20 atom % to 50 atom % with respect to the total amount of components of the second glass.
5. 5 . The multilayer ceramic capacitor of claim 1 , wherein the first glass further comprises lithium (Li), sodium (Na), iron (Fe), barium (Ba), calcium (Ca), zinc (Zn), boron (B), silicon (Si), tin (Sn) or a combination thereof.
6. 6 . The multilayer ceramic capacitor of claim 5 , wherein: the first glass comprises barium (Ba) and zinc (Zn); and a sum of components of barium (Ba) and zinc (Zn) is 50 atom % to 95 atom % with respect to the total amount of components of the first glass.
7. 7 . The multilayer ceramic capacitor of claim 1 , wherein: the first glass and the second glass further comprise sodium (Na); and an atomic ratio of sodium (Na) comprised in the second glass to sodium (Na) comprised in the first glass is more than 2 to 100 or less.
8. 8 . The multilayer ceramic capacitor of claim 1 , wherein: the first glass and the second glass further comprises iron (Fe); and an atomic ratio of iron (Fe) comprised in the second glass to iron (Fe) comprised in the first glass is more than 2 to 100 or less.
9. 9 . The multilayer ceramic capacitor of claim 1 , wherein at least one of the lower layer and the upper layer further comprises a conductive metal.
10. 10 . The multilayer ceramic capacitor of claim 9 , wherein the conductive metal comprises copper (Cu), nickel (Ni), silver (Ag), palladium (Pd), gold (Au), platinum (Pt), tin (Sn), tungsten (W), titanium (Ti), lead (Pb), an alloy thereof, or a combination thereof.
11. 11 . The multilayer ceramic capacitor of claim 1 , wherein the external electrode includes (i) a central portion that includes a central point of a length of the multilayer ceramic capacitor in thickness direction and (ii) a corner portion that includes a corner point of the multilayer ceramic capacitor, and a thickness ratio of corner portion compared to central portion of the external electrode is 0.1 to 0.5.
12. 12 . The multilayer ceramic capacitor of claim 3 , wherein the second glass comprises lithium (Li).
13. 13 . The multilayer ceramic capacitor of claim 12 , wherein the first glass further comprises lithium (Li); and an atomic ratio of lithium (Li) comprised in the second glass to lithium (Li) comprised in the first glass is more than 1.
14. 14 . A method of manufacturing a multilayer ceramic capacitor, the manufacturing method comprising: applying a first paste for forming a lower layer of an external electrode to a surface of a capacitor body comprising a dielectric layer and an internal electrode layer, the lower layer comprising a first glass; forming the lower layer by sintering the first paste; applying a second paste for forming an upper layer of the external electrode on the lower layer, the upper layer comprising a second glass; and forming the upper layer by sintering the second paste, wherein the first paste includes a first glass composition that forms a first glass, and the first glass composition comprises aluminum oxide (Al 2 O 3 ) in an amount of more than 0 parts by mole to 8 parts by mole or less with respect to a total amount of 100 parts by mole of the first glass composition; and wherein the second paste includes a second glass composition that forms a second glass, and the second glass composition comprises aluminum oxide (Al 2 O 3 ) in an amount of 10 parts by mole or more to 20 parts by mole or less with respect to a total amount of 100 parts by mole of the second glass composition.
15. 15 . A method of manufacturing a multilayer ceramic capacitor, the manufacturing method comprising: applying a first paste for forming a lower layer of an external electrode to a surface of a capacitor body comprising a dielectric layer and an internal electrode layer, the lower layer comprising a first glass; applying a second paste for forming an upper layer of the external electrode on first the paste, the upper layer comprising a second glass; and forming the external electrode comprising the lower layer and the upper layer by sintering the capacitor body applied with the first paste and the second paste, wherein the first paste includes a first glass composition that forms a first glass, and the first glass composition comprises aluminum oxide (Al 2 O 3 ) in an amount of more than 0 parts by mole to 8 parts by mole or less with respect to a total amount of 100 parts by mole of the first glass composition, and wherein the second paste includes a second glass composition that forms a second glass, and the second glass composition comprises aluminum oxide (Al 2 O 3 ) in an amount of 10 parts by mole or more to 20 parts by mole or less with respect to a total amount of 100 parts by mole of the second glass composition.
16. 16 . The method of manufacturing the multilayer ceramic capacitor of claim 14 , wherein the first glass composition further comprises barium oxide (BaO), calcium oxide (CaO), zinc oxide (ZnO), boron oxide (B 2 O 3 ), silicon dioxide (SiO 2 ), or a combination thereof.
17. 17 . The method of manufacturing the multilayer ceramic capacitor of claim 16 , wherein, with respect to the total amount of 100 parts by mole of the first glass composition: barium oxide (BaO) is comprised in an amount of 10 parts by mole to 40 parts by mole; calcium oxide (CaO) is comprised in an amount of 1 part by mole to 20 parts by mole; zinc oxide (ZnO) is comprised in an amount of 10 parts by mole to 40 parts by mole; boron oxide (B 2 O 3 ) is comprised in an amount of 10 parts by mole to 40 parts by mole; and silicon dioxide (SiO 2 ) is comprised in an amount of 1 part by mole to 20 parts by mole.
18. 18 . The method of manufacturing the multilayer ceramic capacitor of claim 14 , wherein the second glass composition further comprises lithium oxide (Li 2 O), sodium oxide (Na 2 O), barium oxide (BaO), calcium oxide (CaO), zinc oxide (ZnO), boron oxide (B 2 O 3 ), silicon dioxide (SiO 2 ), iron oxide (Fe 2 O 3 ), or a combination thereof.
19. 19 . The method of manufacturing the multilayer ceramic capacitor of claim 18 , wherein, with respect to the total amount of 100 parts by mole of the second glass composition: lithium oxide (Li 2 O) is comprised in an amount of 1 part by mole to 20 parts by mole; sodium oxide (Na 2 O) is comprised in an amount of 1 part by mole to 20 parts by mole; barium oxide (BaO) is comprised in an amount of 10 parts by mole to 40 parts by mole; calcium oxide (CaO) is comprised in an amount of 1 part by mole to 20 parts by mole; zinc oxide (ZnO) is comprised in an amount of 1 part by mole to 20 parts by mole; boron oxide (B 2 O 3 ) is comprised in an amount of 10 parts by mole to 40 parts by mole; silicon dioxide (SiO 2 ) is comprised in an amount of 1 part by mole to 20 parts by mole; and iron oxide (Fe 2 O 3 ) is comprised in an amount of 0.1 part by mole to 10 parts by mole.
20. 20 . The method of manufacturing the multilayer ceramic capacitor of claim 14 , wherein at least one of the first paste and the second paste further comprises a conductive metal.

Description

CROSS-REFERENCE TO RELATED APPLICATION This application claims priority to and the benefit of Korean Patent Application No. 10-2023-0145384 filed in the Korean Intellectual Property Office on Oct. 27, 2023, the entire contents of which is incorporated herein by reference. BACKGROUND (a) Technical Field The present disclosure relates to a multilayer ceramic capacitor and a manufacturing method thereof. (b) Description of the Related Art As electronic components using a ceramic material, there are a capacitor, an inductor, a piezoelectric element, a varistor, a thermistor, and the like. Among ceramic electronic components, a multilayer ceramic capacitor (MLCC) may be used in various electronic devices due to advantages such as a small size, a high capacitance, an easy mounting feature, and the like. For example, a multilayer ceramic capacitor may be used in a chip type condenser mounted on a board of several electronic products such as image devices, for example, liquid crystal displays (LCD), plasma display panels (PDP), or the like, computers, personal portable terminals, smartphones, and the like, to serve to charge or discharge electricity therein or therefrom. Recently, with the miniaturization of electronic products, multilayer ceramic capacitors are also required to be miniaturized and to have ultra-high capacitance. For this purpose, the thickness of the dielectric layer and internal electrode layer is reduced, and a multilayer ceramic capacitor having a structure in which a greater number of dielectric layers and internal electrode layers are stacked is being developed. These ultra-small and ultra-high-capacitance multilayer ceramic capacitors are recently used in fields that require a high level of reliability, such as electric vehicles, and accordingly, high reliability is required for such capacitors. SUMMARY An embodiment attempts to provide a multilayer ceramic capacitor having an excellent reliability. Another embodiment attempts to provide a method of manufacturing a multilayer ceramic capacitor. A multilayer ceramic capacitor may include a capacitor body including a dielectric layer and an internal electrode layer, and an external electrode disposed outside the capacitor body, where the external electrode includes a lower layer positioned on a cross-section of the capacitor body to be electrically connected to the internal electrode layer, and an upper layer to cover the lower layer and positioned on the lower layer, where the lower layer includes a first glass that may include aluminum (Al) in an amount of more than 0 atom % to 8 atom % or less with respect to a total amount of components of the first glass, and where the upper layer includes a second glass that may include aluminum (Al) in an amount of 10 atom % or more to 20 atom % or less with respect to a total amount of components of the second glass. A ratio of the amount of aluminum (Al) included in the second glass to the amount of aluminum (Al) included in the first glass may be more than 2 to 100 or less. The second glass may further include lithium (Li), sodium (Na), iron (Fe), barium (Ba), calcium (Ca), zinc (Zn), boron (B), silicon (Si), tin (Sn) or a combination thereof. The second glass may include silicon (Si), and a sum of components of aluminum (Al) and silicon (Si) is 20 atom % to 50 atom % with respect to the total amount of components of the second glass. The first glass may further include lithium (Li), sodium (Na), iron (Fe), barium (Ba), calcium (Ca), zinc (Zn), boron (B), silicon (Si), tin (Sn) or a combination thereof. The first glass may include barium (Ba) and zinc (Zn), and a sum of components of barium (Ba) and zinc (Zn) is 50 atom % to 95 atom % with respect to the total amount of components of the first glass. The first glass and the second glass may further include sodium (Na), and an atomic ratio of sodium (Na) included in the second glass to sodium (Na) included in the first glass may be more than 2 to 100 or less. The first glass and the second glass may further include iron (Fe), and an atomic ratio of iron (Fe) included in the second glass to iron (Fe) included in the first glass may be more than 2 to 100 or less. At least one of the lower layer and the upper layer may further include a conductive metal. The conductive metal may include copper (Cu), nickel (Ni), silver (Ag), palladium (Pd), gold (Au), platinum (Pt), tin (Sn), tungsten (W), titanium (Ti), lead (Pb), an alloy thereof, or a combination thereof. The external electrode may include (i) a central portion that includes a central point of a length of the multilayer ceramic capacitor in thickness direction and (ii) a corner portion that includes a corner point of the multilayer ceramic capacitor, and a thickness ratio of corner portion compared to central portion of the external electrode may be 0.1 to 0.5. The second glass may include lithium (Li). The first glass may further include lithium (Li), and an atomic ratio of lithium (Li) included in t