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US-12622070-B2 - Encapsulant film based on functionalized polyolefins

US12622070B2US 12622070 B2US12622070 B2US 12622070B2US-12622070-B2

Abstract

The invention relates to a film comprising a functionalized polyolefin polymer and to the use of the film as an encapsulant film for a photovoltaic module. The functionalized polyolefin polymer is a polymer selected from: (a) a propylene copolymer, (b) a propylene terpolymer, (c) an ethylene terpolymer, and (d) a polymer mixture comprising any combination of polymers (a) to (c). Further, the functionalized polyolefin polymer comprises <0.8 wt %, of an inorganic metal oxide such as alumina, based on the total weight of the functionalized polyolefin polymer. The invention further relates to an encapsulated solar cell comprising encapsulant layers comprising the film. The invention further relates to a photovoltaic module comprising the encapsulated solar cell and to a process for making the photovoltaic module.

Inventors

  • Robbert Duchateau
  • Lidia JASINSKA-WALC
  • Miloud BOUYAHYI
  • Jakub Kruszynski
  • Weronika Nowicka
  • Wojciech Szot

Assignees

  • SABIC GLOBAL TECHNOLOGIES B.V.

Dates

Publication Date
20260505
Application Date
20230616
Priority Date
20220616

Claims (16)

  1. 1 . A film comprising a functionalized polyolefin polymer, wherein the functionalized polyolefin polymer is a polymer selected from the group consisting of: a. a propylene copolymer comprising i. ≥95.0 mol % and ≤99.95 mol % of polymeric units derived from propylene, and ii. ≥0.05 mol % and ≤5.0 mol % of polymeric units derived from a functionalized olefin monomer, based on the total moles of all polymeric units constituting the propylene copolymer; b. a propylene terpolymer comprising i. ≥80.0 mol % and ≤98.95 mol % of polymeric units derived from propylene; ii. ≥0.1 mol % and ≤19.95 mol % of polymeric units derived from a first olefin monomer comprising either 2, or 4 to 8 carbon atoms; and iii. ≥0.05 mol % and ≤5.0 mol % of polymeric units derived from a functionalized olefin monomer, based on the total moles of all polymeric units constituting the propylene terpolymer; c. an ethylene terpolymer comprising: i. ≥80.0 mol % and ≤98.95 mol % of polymeric units derived from ethylene, ii. ≥0.1 mol % and ≤19.95 mol % of polymeric units derived from a second olefin monomer comprising 3 to 8 carbon atoms; and iii. ≥0.05 mol % and ≤5.0 mol % of polymeric units derived from a functionalized olefin monomer; based on the total moles of all polymeric units constituting the ethylene terpolymer; and d. a polymer mixture comprising any combination of polymers (a) to (c); wherein the functionalized olefin monomer is a monomer selected from: i. a hydroxyl group containing olefin monomer having 4 to 12 carbon atoms; ii. a carboxylic acid containing olefin monomer having 2 to 12 carbon atoms; and iii. an esterified olefin monomer represented by the formula: wherein R 1 is selected from a hydrocarbyl group having 2 to 10 carbon atoms; wherein R 2 is selected from a hydrocarbyl group having 2 to 10 carbon atoms, and wherein ‘n’ is an integer from 1 to 3 and ‘m’ is an integer from 0 to 4, wherein the functionalized polyolefin polymer comprises ≤0.8 wt % of inorganic metal oxide, based on the total weight of the functionalized polyolefin polymer and determined using Inductively Coupled Plasma Mass Spectrometry.
  2. 2 . The film according to claim 1 , wherein (i) the carboxylic acid containing olefin monomer is selected from the group consisting of acrylic acid, 3-butenoic acid, 4-pentenoic acid, 5-hexenoic acid, 10-undecenoic acid, 5-norbornene-2-carboxylic acid and 5-norbornene-2-acetic acid; and/or wherein (ii) the hydroxyl group containing olefin monomer is selected from the group consisting of 3-buten-1-ol, 5-hexen-1-ol, 7-octen-1-ol, and 10-undecen-1-ol.
  3. 3 . The film according to claim 1 , wherein (i) the first olefin monomer comprising either 2 or 4 to 8 carbon atoms, is a monomer selected from the group consisting of ethylene, 1-butene, 1-hexene, 4-methyl-1-pentene, vinylcyclohexane, and 1-octene; and/or wherein (ii) the second olefin monomer comprising 3 to 8 carbon atoms is a monomer selected from the group consisting of propylene, 1-butene, 1-hexene, 4-methyl-1-pentene, vinylcyclohexane, and 1-octene.
  4. 4 . The film according to claim 1 , wherein the functionalized polyolefin polymer is selected from poly(C 3 -co-C 2 -co-C 6 OH), poly(C 3 -co-C 4 -co-C 6 OH), poly(C 3 -co-C 6 -co-C 6 OH), poly(C 3 -co-C 8 -co-C 6 OH), poly(C 3 -co-C 6 OH), poly(C 3 -co-C 2 -co-C 6 OX), poly(C 3 -co-C 6 -co-C 6 OX), and combinations thereof, wherein C 2 represents ethylene monomer, C 3 represents propylene monomer, C 4 represents 1-butene monomer, C 6 represents 1-hexene monomer, C 8 represents 1-octene monomer and C 6 OH represents 5-hexen-1-ol monomer, and ‘X’ represents a moiety derived from citric acid, citric acid anhydride, gluconic acid, glucaric acid, isocitric acid, tartaric acid, succinic acid, succinic acid anhydride, fumaric acid, malic acid, maleic acid anhydride, itaconoic acid, itaconoic acid anhydride, oxalic acid, trimesic acid, 1,2,4-benzenetricarboxylix-1,2-anhydride, propan-1,2-3-tricarboxylic acid, 2-phosphonobutane-1,2,4-tricarboxylic acid (PBTC).
  5. 5 . The film according to a claim 1 , wherein the functionalized polyolefin polymer has: i) an inorganic metal oxide content of ≥0.0 wt % and ≤0.8 wt %, based on the total weight of the functionalized polyolefin copolymer and determined using Inductively Coupled Plasma Mass Spectrometry; and/or ii) a peak melting temperature (T m ) of ≥50.0° C. and ≤120.0° C., as determined using differential scanning calorimetry (DSC) in accordance with ASTM D3418 (2008).
  6. 6 . The film according to claim 1 , wherein the functionalized polyolefin polymer has: i) a hydroxyl functional group content of ≥0.1 and ≤1.0 mol %, when determined using NMR spectroscopy; and/or ii) a Polydispersity Index (PDI) of ≥1.5 and ≤6.0, wherein PDI is calculated by dividing the weight average molecular weight (M W ) by the number average molecular weight (M n ) and wherein each of M W and M n are determined in accordance with ASTM D6474-12.
  7. 7 . The film according to claim 1 , wherein the functionalized polyolefin polymer has: i) a weight average molecular weight (M W ) ≥75.0 kg/mol and ≤150.0 kg/mol, determined in accordance with ASTM D6474-12; and/or ii) a crystallization temperature (T c ) of ≥20° C. and ≤80° C., as determined using differential scanning calorimetry (DSC) in accordance with ASTM D3418 (2008); and/or iii) a glass transition temperature (T g ) of ≥−50.0° C. and ≤5.0° C., as determined using dynamic mechanical thermal analysis (DMTA) in accordance with ISO 6721-10:2015.
  8. 8 . The film according to claim 1 , wherein the film exhibits: a. a volume resistivity of ≥1.0×10 13 and ≤3.0×10 16 , when determined in accordance with ASTM D257-14 (2021) at an applied voltage of 1000V for a time period of 600 seconds and at a temperature of 25° C.; and/or b. an optical transmittance of ≥30.0% and ≤95.0%, when determined in accordance with ASTM D1003 (2021).
  9. 9 . The film according to claim 1 , wherein the film exhibits: a. a tensile strength at break of ≥15.0 MPa and ≤60.0 MPa, when determined in accordance with ASTM D882 (2018); and/or b. a tensile modulus of ≥30.0 MPa and ≤130.0 MPa, when determined in accordance with ASTM D882 (2018).
  10. 10 . A process for preparing the film according to claim 1 , wherein the process comprises at least one step involving any one of film extrusion and casting, or compression molding.
  11. 11 . An encapsulated solar cell comprising a solar cell positioned between a first encapsulant layer and a second encapsulant layer, wherein at least one of the first encapsulant layer or the second encapsulant layer comprises or consists of the film according to claim 1 , further wherein the solar cell is positioned such that the first encapsulant layer and the second encapsulant layer are joined so as to at least partially encapsulate the solar cell.
  12. 12 . A photovoltaic module comprising the encapsulated solar cell according to claim 11 .
  13. 13 . The photovoltaic module of claim 12 , wherein: the photovoltaic module comprises a front layer, a back layer, and the encapsulated solar cell, wherein the encapsulated solar cell is positioned between the front layer and the back layer; and the front layer and/or the back layer comprises a material selected from the group consisting of a polypropylene composition, glass, polycarbonate composition, and any combinations thereof.
  14. 14 . A process for making the photovoltaic module of claim 12 , wherein: the photovoltaic module comprises a front laver, a back layer, and the encapsulated solar cell, wherein the encapsulated solar cell is positioned between the front layer and the back laver, and the process comprises the step of: assembling the front layer, the first encapsulant layer, the solar cell, the second encapsulant layer and the back layer to form a photovoltaic assembly such that the solar cell is positioned between the first encapsulant layer and the second encapsulant layer; and the second encapsulant layer is in direct contact with the back layer; heating the photovoltaic assembly at a temperature such that at least a portion of the first encapsulant layer and the second encapsulant layer melt to form a melted photovoltaic assembly comprising the solar cell; pressing the melted photovoltaic assembly under heated conditions and forming the laminated photovoltaic module; and cooling the laminated photovoltaic module to ambient temperature and obtaining the photovoltaic module.
  15. 15 . An encapsulant film for a photovoltaic module, wherein the encapsulant film comprises the film of claim 1 .
  16. 16 . A process for making a photovoltaic module, the method comprising positioning a solar cell between a first encapsulant film and a second encapsulant film, wherein the first encapsulant film, the second encapsulant film, or a combination thereof comprises the film of claim 1 .

Description

CROSS REFERENCE TO RELATED APPLICATIONS This application is a National Stage application of PCT/EP2023/066299, filed Jun. 16, 2023, which claims the benefit of European Application No. 22179456.3, filed Jun. 16, 2022, both of which are incorporated by reference in their entirety herein. FIELD OF INVENTION The invention relates to a film comprising a polar group functionalized polyolefin polymer and to the use of the film as an encapsulant film for a photovoltaic module. The invention further relates to an encapsulated solar cell comprising one or more encapsulant layers comprising the film. The invention further relates to a photovoltaic module comprising the encapsulated solar cell and to a process for making the making such a photovoltaic module. BACKGROUND Polymeric materials such as ethylene-vinyl acetate copolymers (EVA) and polyolefin elastomers (POE), are commonly used as encapsulants in photovoltaic modules. Some desirable properties and functions of such polymeric materials include (i) high electrical resistance (or volume resistivity) (ii) excellent moisture and gas barrier property, (iii) ease of processing, (iv) excellent optical transmittance, and (v) suitable mechanical properties such as tensile modulus. Polymeric material such as ethylene-vinyl acetate copolymers (EVA) and polyolefins such as polyolefin elastomers (POE) have been used for preparing polymeric encapsulants suitable for photovoltaic modules and other allied applications. However, EVA copolymer, owing to its polarity, suffer from having low volume resistivity and low moisture barrier properties, as compared to a conventional polyolefin elastomers. Further, it has been observed that EVA based films progressively darken on prolonged exposure to sunlight due to chemical degradation, which adversely affects the utility of the film. In addition, EVA resins tend to degrade on account of prolonged exposure to atmospheric moisture induced through hydrolysis. Additionally, hydrolysis of EVA forms acetic acid as an undesired side product, which is harmful for the electronic components of a photovoltaic module. To circumvent these shortcomings of EVA copolymers, polyolefin polymers have been investigated as a possible alternative. Despite the benefits that a polyolefin encapsulant film may offer, for example of having high volume resistivity, low gas and moisture permeability, polyolefins have their own set of shortcomings. Therefore, it is an object of the present invention to provide a film, which can be used as an encapsulant film in a photovoltaic module having one or more of the following advantages of (i) desirably high electrical resistance (or volume resistivity), (ii) excellent adhesion property (iii) excellent moisture and gas barrier property, (iv) ease of processability, (v) excellent optical transmittance, (vi) recyclability and (vii) suitable mechanical properties such as tensile modulus. DESCRIPTION Accordingly, one or more objectives of the present invention is achieved by a film comprising a functionalized polyolefin polymer, wherein the functionalized polyolefin polymer is a polymer selected from the group consisting of: a. a propylene copolymer, comprising i. ≥95.0 mol % and ≤99.95 mol %, preferably ≥98.0 mol % and ≤99.95 mol %, preferably ≥99.0 mol % and ≤99.9 mol %, preferably ≥99.5 mol % and ≤99.9 mol %, of polymeric units derived from propylene, andii. ≥0.05 mol % and ≤5.0 mol %, preferably ≥0.05 mol % and ≤2.0 mol %, preferably ≥0.1 mol % and ≤1.0 mol %, preferably ≥0.1 mol % and ≤0.5 mol %, of polymeric units derived from a functionalized olefin monomer, based on the total moles of all polymeric units constituting the propylene copolymer,b. a propylene terpolymer, comprising i. ≥80.0 mol % and ≤98.95 mol %, preferably ≥88.0 mol % and ≤98.0 mol %, preferably ≥90.0 mol % and ≤96.0 mol %, of polymeric units derived from propylene;ii. ≥0.1 mol % and ≤19.95 mol %, preferably ≥1.0 mol % and ≤10.0 mol %, preferably ≥3.5 mol % and ≤9.9 mol %, of polymeric units derived from a first olefin monomer comprising either 2, or 4 to 8 carbon atoms, preferably the first olefin monomer comprises 2 or 6 carbon atoms; andiii. ≥0.05 mol % and ≤5.0 mol %, preferably ≥0.1 mol % and ≤2.0 mol %, preferably ≥0.1 mol % and ≤0.5 mol %, of polymeric units derived from a functionalized olefin monomer, based on the total moles of all polymeric units constituting the propylene terpolymer;c. an ethylene terpolymer, comprising: i. ≥80.0 mol % and ≤98.95 mol %, preferably ≥90.0 mol % and ≤97.0 mol %, of polymeric units derived from ethylene,ii. ≥0.1 mol % and ≤19.95 mol %, preferably ≥2.5 mol % and ≤9.9 mol %, of polymeric units derived from a second olefin monomer comprising 3 to 8 carbon atoms, preferably the second olefin monomer comprises 8 carbon atoms; andiii. ≥0.05 mol % and ≤5.0 mol %, preferably ≥0.1 mol % and ≤0.5 mol %, of polymeric units derived from a functionalized olefin monomer; based o