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US-12624190-B2 - Antibacterial antistatic composition and volatile corrosion inhibitor film including the same

US12624190B2US 12624190 B2US12624190 B2US 12624190B2US-12624190-B2

Abstract

The present application relates to an antistatic composition, which includes a conductive structure formed by connecting a modified graphene oxide or a modified carbon nanotube with a conductive polymer; silver nanoparticles; and a solvent, and a corrosion inhibition film including the same. The corrosion inhibition film of the present application has excellent antibacterial activity and excellent corrosion inhibiting ability.

Inventors

  • Gi Moon YOO
  • Gwan Yeong KIM

Assignees

  • DAEJIN ADVANCED MATERIALS INC.

Dates

Publication Date
20260512
Application Date
20211223
Priority Date
20211110

Claims (12)

  1. 1 . An antibacterial antistatic composition, comprising: a conductive structure which comprises a carbon nanotube or graphene oxide in which one or more oligomers selected from an acrylic oligomer and a urethane oligomer bind to its surface through a branch linkage, and a conductive polymer connected to the oligomer; silver nanoparticles; and a solvent, wherein the oligomer comprises one or more of n number of first units with an acrylic group and m number of second units with a urethane group, wherein the first unit is represented by Formula 4, and the second unit is represented by Formula 5, wherein X 1 is a direct linkage, or a urethane group or a C 1 -C 10 alkylene group, X 2 is a C 1 -C 10 alkylene group, X 3 is a direct linkage, O or S, m is an integer of 0 to 1000, n is an integer of 0 to 1000, and n+m is an integer of 1 to 1000.
  2. 2 . The antibacterial antistatic composition of claim 1 , comprising, based on the total weight of the composition, 1 to 49 wt % of the conductive structure; 0.1 to 1 wt % of the silver nanoparticles; and 50 to 98 wt % of the solvent.
  3. 3 . The antibacterial antistatic composition of claim 1 , wherein the silver nanoparticle has a diameter of 0.1 nm to 100 nm.
  4. 4 . The antibacterial antistatic composition of claim 1 , wherein the silver nanoparticle is coated with a silicone-based compound.
  5. 5 . The antibacterial antistatic composition of claim 1 , wherein the composition has a bacteria inhibition rate of 90% or more in an antibacterial test of measuring a bacteria reduction rate after the contact of a sample surface with a bacterial culture for 24 hours in accordance with KSM ISO 22196.
  6. 6 . The antibacterial antistatic composition of claim 1 , wherein the conductive polymer is one or more of poly(3,4-ethylenedioxythiopene) (PEDOT) and polystyrene sulfonic acid (PSS), and wherein the PEDOT is represented by Formula 1, 2, or 3 below, wherein A is or —NH.
  7. 7 . The antibacterial antistatic composition of claim 1 , wherein the carbon nanotube or graphene oxide:the oligomer:the conductive polymer are connected in a weight ratio of 2:1:8 to 1:0.2:100.
  8. 8 . The antibacterial antistatic composition of claim 1 , wherein the conductive structure is represented by Formulas 8 to 11 below: wherein, in Formula 8, R is each of n and m is independently an integer of 0 to 1000, and k is an integer of 1 to 10,000,000, wherein, in Formula 9, R is each of n and m is independently an integer of 0 to 1000, and each of k and i is independently an integer of 1 to 10,000,000, wherein, in Formula 10, R is each of n and m is independently an integer of 0 to 1000, and k is an integer of 1 to 10,000,000, wherein, in Formula 11, R is each of n and m is independently an integer of 0 to 1000, and each of k and i is independently an integer of 1 to 10,000,000.
  9. 9 . A corrosion inhibition film, comprising: a corrosion inhibiting resin layer; and an antistatic coating layer formed of the antistatic composition of claim 1 at least one surface of the corrosion inhibiting resin layer.
  10. 10 . The corrosion inhibition film of claim 9 , wherein the corrosion inhibiting resin layer is formed of a composition comprising 70 to 90 wt % of a resin; 1 to 5 wt % of a nitrite; 1 to 5 wt % of a moisture absorbent, based on the total weight of the composition.
  11. 11 . The corrosion inhibition film of claim 10 , wherein the resin is at least one selected from the group consisting of a polyolefin, polystyrene, an acrylonitrile-butadiene-styrene copolymer, polyethylene terephthalate and a polyamide.
  12. 12 . The corrosion inhibition film of claim 11 , wherein the polyolefin is at least one selected from the group consisting of low-density polyethylene (LDPE), linear low-density polyethylene (LLDPE), metallocene polyethylene, high-density polyethylene (HDPE), polypropylene and ethylene vinyl acetate, and has a weight average molecular weight of 10,000 to 20,000 g/mol.

Description

CROSS-REFERENCE TO RELATED APPLICATIONS This application is a National Phase application of PCT Application No. PCT/KR2021/019716 filed on Dec. 23, 2021 which claims priority to Korean Patent Application No. 10-2021-0153984 filed on Nov. 10, 2021. The entire disclosures of the applications identified in this paragraph are incorporated herein by reference. TECHNICAL FIELD The present application relates to an antistatic composition and a corrosion inhibition film to which antistatic coating is applied. BACKGROUND ART With the development of modern society, plastics, which are lighter than metal materials, incorrodible and freely formed in various forms, are widely used in everyday products and advanced electronic materials. Most plastics are electrical insulators, and when materials are in contact with each other, rub against each other or are separated from each other, the same amount of charge with different polarities are charged to both sides, easily leading to static electricity. Such static electricity is one of the factors causing problems in all industrial fields, and it can act as a factor that reduces productivity in a plastic molding process. Particularly, in the semiconductor manufacturing process, a circuit may be damaged by the discharge of static electricity, and there are many problems such as a malfunction of precision products such as communication instruments and major measuring instruments. Since a malfunction is caused by the static electricity problem, it is necessary to solve problems of contamination and defects caused by harmful substances such as dust. Particularly, as the need for removing static electricity and managing contaminants is emphasized, it was necessary to develop an antistatic composition to which an antistatic functional material having additional electrical conductivity to the existing properties was applied. Currently, metal-related packaging films have simple functions such as corrosion protection, and methods such as anti-corrosion paper, anti-corrosion liquid, anti-corrosion grease, anti-corrosion oil, anti-corrosion powder to prevent corrosion greatly affects the quality of metal products to be packed. However, such anti-corrosion methods for metal products have disadvantages of increased packaging costs, low productivity, and inconvenience caused by an additional process. Therefore, the development of a corrosion inhibition film that improves the above-described disadvantages was required. SUMMARY Technical Problem A problem to be solved by the present application is directed to providing an antistatic composition, which solves the above-described problems, improves the dispersibility of a carbon material, improves electrical properties and has an antibacterial function. Another problem to be solved by the present application is directed to providing a corrosion inhibition film having an antibacterial function and a corrosion inhibiting function. Technical Solution One aspect of the present application provides an antibacterial antistatic composition, which includes: a conductive structure which includes a carbon nanotube or graphene oxide in which one or more oligomers selected from an acrylic oligomer and a urethane oligomer bind to its surface through a branch linkage, and a conductive polymer connected to the oligomer; silver nanoparticles; and a solvent. In one embodiment of the present application, the composition may include 1 to 49 wt % of the conductive structure; 0.1 to 1 wt % of the silver nanoparticles; and 50 to 98 wt % of the solvent based on the total weight of the composition. In one embodiment of the present application, the silver nanoparticle may have a diameter of 0.1 nm to 100 nm. In one embodiment of the present application, the silver nanoparticle may be coated with a silicone-based compound. In one embodiment of the present application, the composition may have a bacteria inhibition rate of 90% or more in an antibacterial test of measuring a bacteria reduction rate after the contact of a sample surface with a bacterial culture for 24 hours in accordance with KSM ISO 22196. In one embodiment of the present application, the conductive polymer may be selected from the group consisting of polythiophene and a polythiophene derivative, polystyrene and a polystyrene derivative, polyaniline and a polyaniline derivative, polypyrrole and a polypyrrole derivative, and a combination thereof. In one embodiment of the present application, the conductive polymer may be one or more of poly(3,4-ethylenedioxythiopene) (PEDOT) and polystyrene sulfonic acid (PSS). In one embodiment of the present application, the PEDOT may have a plurality (more than one) of functional groups having an NH group. In one embodiment of the present application, the PEDOT unit may be represented by Formula 1, 2 or 3 below. Here, A is or —NH. In one embodiment of the present application, the oligomer may include n number of first units with an acrylic group and m number of second